SALCs

No cresol is obtained if sodium hydroxide alone is used, presumably because the fused sodium hydroxide has no solvent action upon the sodium p-toluene-sulphonate. Potassium hydroxide alone gives excellent results, as do also mixtures of Sodium and potassium hydroxide containing not less than 28 per cent, of potassium hydroxide. The experimental details utilise the minimum amount of potassium hydroxide for the salce of economy. 

The above diagram indieates how the SALC-AOs are formed from the Is,2s, and 2p N... 

Baek transformation into the original basis will generate the expeeted results for the le" MOs (expeeted eombinations of SALC-AOs). 

Using D2h symmetry and labeling the orbitals (fi-fi2) as shown above proeeed by using the orbitals to define a redueible representation.whieh may be subsequently redueed to its irredueible eomponents. Use projeetors to find the SALC-AOs for these irreps. 

Sinee there are only two SALC-AOs and both are of different symmetry types these SALC-AOs are MOs and the 2x2 Hamiltonian matrix reduees to 2 1x1 matriees. 

Projeetors are used to find the SALC-AOs for these irredueible representations. 

Projeetors are used to find the SALC-AOs for these irredueible representations. Define C3 = 120 degree rotation, C3 = 240 degree rotation,... 

This 4x4 symmetry bloek faetors to two 2x2 bloeks where one 2x2 bloek ineludes the SALC-AOs... 

Drawing an energy level diagram using these SALC-AOs would result in the following ... 

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The hydrogen group orbitals are referred to as symmetry adjusted linear combinations (SALC). Although their development will not be shown here, the molecular orbital diagrams for other tetrahedral molecules are similar. 

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Normalization of this SALC-AO (and representing the SALC-AOs with (f>) yields ... 

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