Ring dyeing

In order to observe such high-resolution fluorescence excifafion spectra, the laser must have a very small line width. To achieve this a ring dye laser, a modification of the dye laser described in Section 9.2.10, is used a line width as small as 0.5 MFIz (1.5 x 10 cm ) can be obtained. 

A remarkable feature of these spectra is the resolution of individual rotational lines in such large molecules. [Note that the expanded specttum in, for example. Figure 9.47(a) covers only 5000 MFIz (0.17 cm )]. This is due partly to the very low rotational temperature (3.0 K for aniline and 2.2 K for aniline Ar), partly to the reduction of the Doppler broadening and partly to the very high resolution of the ring dye laser used. 

One variation in dye laser constmction is the ring dye laser. The laser cavity is a reentrant system, so that the laser light can circulate in a closed loop. The ring stmcture provides a high degree of stabiUty and a narrow spectral width. The spectral width of a conventional dye laser on the order of 40 GH2 is narrowed to a value as small as a few MH2. Such systems offer very high resolution in spectroscopic appHcations. 

ESO VLT/Max Planck CW Dye Laser. The MPI is developing a CW dye laser for deployment on one ESO 8-m VLT telescope in 2004 (Eig. 13). The oscillator is a Coherent 899 ring dye laser, with a 2-5 W output, pumped by a 10 W, Coherent Verdi frequency-doubled Nd YAG laser. The beam is amphfied in a four-pass amphfier with 4 high velocity dye jets pumped with 4 10 W Verdi lasers. The system utihzes Rhodamine 6G in ethylene glycol however, because of the high pump power, the dye degrades quickly, and must... 

The advent of ultrafast pump-probe laser techniques62 and their marriage with the TOF method also enables study of internal ion-molecule reactions in clus-ters.21,63-69 The apparatus used in our experiments is a reflectron TOF mass spectrometer coupled with a femtosecond laser system. An overview of the laser system is shown in Figure 4. Femtosecond laser pulses are generated by a colliding pulse mode-locked (CPM) ring dye laser. The cavity consists of a gain jet, a... 

Indigo Ring Dyeing Chemistry of Indigo Dyeing. Virkler Company, Charlotte, NC, http //www.virkler.com/expertise/html/chemistry.html... 

The conversion of squaraine 19a to the rotaxane 18 D 19a causes a modest red-shift only in both absorption (10 nm) and emission (7 nm) but an approximately threefold decrease in quantum yield. The addition of two triazole rings (dye 19b) did not significantly alter the quantum yield of 17b (Table 4). A macrocycle-induced quenching effect was verified by fluorescence titration experiments adding aliquots of 18 to a solution of squaraine 17b in methylene chloride [58]. Treatment of the 18 d 17b psuedorotaxane system with the tetrabutylammonium salts of chloride, acetate, or benzoate leads to the displacement of squaraine 17b from the macrocyclic cavity and the nearly complete restoration of its fluorescence intensity. The 18-induced quenching of 17b does not support the utility of this system as a bioimaging probe however, the pseudorotaxane system 18 Z> 17b acts as an effective and selective anion sensor with NIR fluorescence. 

Some of the earlier experiments were carried out using our home-built colliding pulse modelocked (CPM) ring dye laser. Equipped with two excimer... 

If methyleneindoline-o)-aldehydes are condensed with cyclic amines substituted by an amino group in the aromatic ring, dyes are obtained that can be dimerized either by reaction with cyanuric chloride in a molar ratio of 2 1 or with phosgene. On account of their high substantivity these dyes are suitable for dyeing bleached sulfite pulp [22],... 

The rms linewidth of the dye laser has so far been reduced to 300 Hz relative to a reference cavity with the help of an intracavity ADP phase modulator and a fast servo system which compensates for small rapid optical path fluctuations in the liquid dye jet [24]. A perhaps even more elegant alternative is the external laser frequency stabilizer [25] which compensates for phase and frequency noise after the light has left the laser cavity. J. Hall and coworkers [26] have recently reduced the linewidth of a commercial ring dye laser to sub-Hz levels with such a device. 

As seen by fiber cross-sections of PET at low dyeing temperatures up to 100°C ring dyeing effects were observed whereas at 120°C the fiber is completely dyed. 

Better LF with higher concentration and lower specific surface (pigment particles have better LF than molecular distributed dyes). Equal dye distribution over the fibre cross-section has better LF than ring dyeing with dyes concentrated near the fibre surface. 

Dyeing or printing procedure, degree of fixation, ring dyeing... 

Wise FW, Walmsley lA, Tang CL (1988) Simultaneous formation of solitons and dispersive waves in a femtosecond ring dye-laser. Opt Lett 13 129-131... 

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