Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Replica trick

The mean field treatment of such a model has been presented by Forgacs et al. [172]. They have considered the particular problem of the effects of surface heterogeneity on the order of wetting transition. Using the replica trick and assuming a Gaussian distribution of 8 Vq with the variance A (A/kT < 1), they found that the prewetting transition critical point is a function of A and... [Pg.279]

Therefore, the central technical problem is the calculation of averaged value of F = — InZ this can be done using the so-called replica trick ... [Pg.23]

This replica-trick method was used in the Refs. [60,61] for the polymer network free energy calculation. For averaging of Z"-value over the ensemble of realizations the probability distribution should be chosen. The authors of Refs. [60,61] have used the condition of the thermodynamical equilibrium for the Gibbs probability distribution corresponding to the conditions of network preparation. To our mind, it is a beautiful idea but it should be considered more deeply because not all the types of networks can be described in such a way - many networks cannot be prepared under any equilibrium conditions. Using some additional tube-like approximations, the authors have obtained rather simple results for network elastic constants and for some other parameters. [Pg.23]

Dipolar fluid excess chemical potential. A closed expression for the evaluation of this quantity can be easily derived in the HNC approximation using Lee s star function technique [27] and the replica trick [18], leading to... [Pg.322]

Application of the replica trick of Edwards which is based on the identity... [Pg.38]

As far we consider the case of quenched disorder, the free energy of the system is obtained by averaging the logarithm of the partition function Z over the disorder distribution [15] this amounts to use so-called replica trick [52] writing the logarithm in the... [Pg.109]

Averaging over disorder The replica trick The numerical results in the previous section reveal that a polymer in a random potential can be viewed as a glassy system. In order to develop this point of view, wc apply the replica method, which has been successfully applied in the study of glassy systems [21]. The replica approach was invented in order to compute quenched averages such as as given in Eq. (10), which is difflcult since it entails averaging a ratio of the... [Pg.244]

In this equation, y is the interaction strength, c(r) the crosslink concentration, the smectic order parameter, and Vz (r) the relative displacement of the rubber matrix. Witkowski and Terentjev [132] evaluated (15) for (r) = 1, which is valid deep in the smectic phase, i.e., far below the smectic-nematic transition. Using the so-called replica trick, they integrated out the rubbery matrix fluctuations and obtained an effective free-energy density that depends only on the layer displacements M(r). Under the restriction that wave vector components along the layer normal dominate over in-layer components, q q, and considering only long-... [Pg.213]

In order to avoid averaging In Z, EA use the so-called replica trick, where one averages quantities such as Z" when n is an integer. The relevance of averaging Z" instead of In Z lies in the relationship... [Pg.230]

The averaging of a logarithm is a difficult problem but with the use of the replica trick we can define F(n)... [Pg.1018]

Inspection of Eq. (7.12) indicates that the replicated system introduced by the multiplication trick is a (n + l)-component mixture composed of the matrix particles and altogether n identical copies (i.e., replicas) of the fluid particles. Each of the copies interacts with the matrix particles, but there are no interactions among different copies. [Pg.347]


See other pages where Replica trick is mentioned: [Pg.197]    [Pg.22]    [Pg.23]    [Pg.164]    [Pg.59]    [Pg.240]    [Pg.1025]    [Pg.197]    [Pg.22]    [Pg.23]    [Pg.164]    [Pg.59]    [Pg.240]    [Pg.1025]    [Pg.132]    [Pg.728]   
See also in sourсe #XX -- [ Pg.23 ]

See also in sourсe #XX -- [ Pg.359 ]

See also in sourсe #XX -- [ Pg.359 ]




SEARCH



Replica

Tricks

© 2024 chempedia.info