Transverse relaxation

At this point, with B, off, the individual nuclear magnetic moments that comprise M begin to dephase (relax transversely) because inhomogeneities in the magnetic field B0... 

The length of time the nucleus spends in the excited state is At. This lifetime is controlled by the rate at which the excited nucleus loses its energy of excitation and returns to the unexcited state. The process of losing energy is called relaxation, and the time spent in the excited state is the relaxation time. There are two principal modes of relaxation longitudinal and transverse. Longitudinal relaxation is also called spin-lattice relaxation transverse relaxation is called spin-spin relaxation. 

Spin-spin relaxation (transverse relaxation) Exchange of energy of excited nuclei with other precessing nuclei. It is characterized by the exponential time constant T2. Also, it determines the envelope of the free induction decay in a perfectly uniform magnetic field and the amplitude of the spin echo. 

The cross-correlation effects between the DD and CSA interactions also influence the transverse relaxation and lead to the phenomenon known as differential line broadening in a doublet [40], cf Figure Bl.13.8. There is a recent experiment, designed for protein studies, that I wish to mention at tire end of this section. It has been proposed by Pervushin etal [4T], is called TROSY (transverse relaxation optimized spectroscopy) and... 

Farrar T C and Stringfellow T C 1996 Relaxation of transverse magnetization for coupled spins Encyclopedia of Nuclear Magnetic Resonance ed D M Grant and R K Harris (Chichester Wiley) pp 4101-7... 

For phase encoding the phase twist is most connnonly varied by incrementing in a series of subsequent transients as tiiis results in a constant transverse relaxation attenuation of the signal at the measurement position. The signal intensity as a fiinction of G is... 

Transverse relaxation weighting is perhaps the most common fonn of contrast imposed on a magnetic... 

In electron spin echo relaxation studies, the two-pulse echo amplitude, as a fiinction of tire pulse separation time T, gives a measure of the phase memory relaxation time from which can be extracted if Jj-effects are taken into consideration. Problems may arise from spectral diflfrision due to incomplete excitation of the EPR spectrum. In this case some of the transverse magnetization may leak into adjacent parts of the spectrum that have not been excited by the MW pulses. Spectral diflfrision effects can be suppressed by using the Carr-Purcell-Meiboom-Gill pulse sequence, which is also well known in NMR. The experiment involves using a sequence of n-pulses separated by 2r and can be denoted as [7i/2-(x-7i-T-echo) J. A series of echoes separated by lx is generated and the decay in their amplitudes is characterized by Ty. ... 

Transverse relaxation time T2 Weight of liquid phase Wl... 

Relaxation refers to all processes which regenerate the Boltzmann distribution of nuclear spins on their precession states and the resulting equilibrium magnetisation along the static magnetic field. Relaxation also destroys the transverse magnetisation arising from phase coherenee of nuelear spins built up upon NMR excitation. 

Spin-spin relaxation is the steady decay of transverse magnetisation (phase coherence of nuclear spins) produced by the NMR excitation where there is perfect homogeneity of the magnetic field. It is evident in the shape of the FID (/fee induction decay), as the exponential decay to zero of the transverse magnetisation produced in the pulsed NMR experiment. The Fourier transformation of the FID signal (time domain) gives the FT NMR spectrum (frequency domain, Fig. 1.7). 

FID Free induction decay, decay of the induction (transverse magnetisation) back to equilibrium (transverse magnetisation zero) due to spin-spin relaxation, following excitation of a nuclear spin by a radio frequency pulse, in a way which is free from the influence of the radiofrequency field this signal (time-domain) is Fourier-transformed to the FT NMR spectrum (frequency domain)... 

K = 63 M 1, Kb = 1.4M-1)47 lithium-7 (K = 14 M 1 K" = 0.5 M 1) 49) and for cesium-133 (K, st 50 M-1, K = 4M 1)S0). In the case of sodium-23, transverse relaxation times could also be utilized to determine off-rate constants k ff = 3 x 105/sec k"ff = 2x 107/sec47,51). Therefore for sodium ion four of the five rate constants have been independently determined. What has not been obtained for sodium ion is the rate constant for the central barrier, kcb. By means of dielectric relaxation studies a rate constant considered to be for passage over the central barrier, i.e. for jumping between sites, has been determined for Tl+ to be approximately 4 x 106/sec 52). If we make the assumption that the binding process functions as a normalization of free energies, recognize that the contribution of the lipid to the central barrier is independent of the ion and note that the channel is quite uniform, then it is reasonable to utilize the value of 4x 106/sec for the sodium ion. 

In simple shear flow where vorticity and extensional rate are equal in magnitude (cf. Eq. (79), Sect. 4), the molecular coil rotates in the transverse velocity gradient and interacts successively for a limited time with the elongational and the compressional flow component during each turn. Because of the finite relaxation time (xz) of the chain, it is believed that the macromolecule can no more follow these alternative deformations and remains in a steady deformed state above some critical shear rate (y ) given by [193] (Fig. 65) ... 

Fig. 7. Theoretical line shapes resulting from an interchange between two NMR frequencies

In polymers one will often particularly be interested in very slow dynamic processes. The solid echo technique just described is still limited by the transverse relaxation time T being of the order of a few ps at most. The ultimate limitation in every NMR experiment however, is not T but the longitudinal relaxation time T, which for 2H in solid polymers typically is much longer, being in the range 10 ms to 10 s. The spin alignment technique (20) circumvents transverse relaxation and is limited by Tx only, thus ultraslow motions become accessible of experiment. 

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