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Related a-Bonded Ligands

METAL ALKYLS. ARYLS, AND HYDRIDES AND RELATED a-BONDED LIGANDS... [Pg.52]

Linkage isomerism This is a special type of structural isomerism in which the differences arise from a particular ligand which may coordinate to a metal ion in more than one way. In Table 1-3 we indicated that a ligand such as thiocyanate could bond to a metal through either the nitrogen or the sulfur atom, and the complex ions [Co(NH3)5(ACS)]2+ and [Co(NH3)5(5CN)]2+ are related as linkage isomers. [Pg.9]

In some cases an alternative sequence involving addition of hydrogen at rhodium prior to complexation of the alkene may operate.11 The phosphine ligands serve both to provide a stable soluble complex and to adjust the reactivity at the metal center. The a-bonded intermediates have been observed for Wilkinson s catalyst12 and for several other related catalysts.13 For example, a partially hydrogenated structure has been isolated from methyl a-acetamidocinnamate.14... [Pg.374]

See other pages where Related a-Bonded Ligands is mentioned: [Pg.59]    [Pg.69]    [Pg.59]    [Pg.69]    [Pg.297]    [Pg.730]    [Pg.262]    [Pg.2522]    [Pg.19]    [Pg.703]    [Pg.5588]    [Pg.365]    [Pg.171]    [Pg.29]    [Pg.28]    [Pg.380]    [Pg.450]    [Pg.703]    [Pg.224]    [Pg.236]    [Pg.108]    [Pg.1447]    [Pg.27]    [Pg.211]    [Pg.79]    [Pg.240]    [Pg.439]    [Pg.279]    [Pg.463]    [Pg.363]    [Pg.375]    [Pg.56]    [Pg.284]    [Pg.479]    [Pg.641]    [Pg.754]    [Pg.931]    [Pg.1019]    [Pg.1160]    [Pg.1171]    [Pg.230]    [Pg.195]   


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A-bonded ligands

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