Regions low temperature

In terms of temperature regions, low-temperature combustion occurs over the range 298-550 K, whereas high-temperature combustion mechanisms dominate at temperatures over 1000 K. Intermediate temperatures, from 550 to 700 K, demonstrate an unusual phenomenon called the negative temperature coefficient (NTQ, which is observed for methane and larger hydrocarbon fuels. As shown in Fig. 3, when the correct alkylperoxy radical chemistry is included in a fuel s combustion mechanism, a NTC range exists (Fig. 3, plot C) where an increase in temperature causes a decrease... 

Below 90 K, [60]fullerene freezes into an orientational glass in which it adopts a simple cubic stmcture [19]. This low temperature stmcture can be traced to the anisotropic electronic stmcture. Alignment of the electron rich regions of... 

The dissipation factor (the ratio of the energy dissipated to the energy stored per cycle) is affected by the frequency, temperature, crystallinity, and void content of the fabricated stmcture. At certain temperatures and frequencies, the crystalline and amorphous regions become resonant. Because of the molecular vibrations, appHed electrical energy is lost by internal friction within the polymer which results in an increase in the dissipation factor. The dissipation factor peaks for these resins correspond to well-defined transitions, but the magnitude of the variation is minor as compared to other polymers. The low temperature transition at —97° C causes the only meaningful dissipation factor peak. The dissipation factor has a maximum of 10 —10 Hz at RT at high crystallinity (93%) the peak at 10 —10 Hz is absent. 

Fig. 6. Schematic ignition diagram for a hydrocarbon+ O2 mixture, with appHcations. Region A, very rapid combustion, eg, a jet engine region B, low temperature ignition, eg, internal combustion engine, safety ha2ards regions C and D, slow oxidation to useful chemicals, eg, 0-heterocycHc compounds in C and alcohols and peroxides in D. Courtesy of Blackwell Scientific PubHcations, Ltd., Oxford (60).

Ethane. Ethane VPO occurs at lower temperatures than methane oxidation but requires higher temperatures than the higher hydrocarbons (121). This is a transition case with mixed characteristics. Low temperature VPO, cool flames, oscillations, and a NTC region do occur. At low temperatures and pressures, the main products are formaldehyde, acetaldehyde (HCHOiCH CHO ca 5) (121—123), and carbon monoxide. These products arise mainly through ethylperoxy and ethoxy radicals (see eqs. 2 and 12—16 and Fig. 1). 

Propane. The VPO of propane [74-98-6] is the classic case (66,89,131—137). The low temperature oxidation (beginning at ca 300°C) readily produces oxygenated products. A prominent NTC region is encountered on raising the temperature (see Fig. 4) and cool flames and oscillations are extensively reported as compHcated functions of composition, pressure, and temperature (see Fig. 6) (96,128,138—140). There can be a marked induction period. Product distributions for propane oxidation are given in Table 1. 

Case Hardening by Surface Deformation. When a metaUic material is plastically deformed at sufficiently low temperature, eg, room temperature for most metals and alloys, it becomes harder. Thus one method to produce a hard case on a metallic component is to plastically deform the surface region. This can be accomplished by a number of methods, such as by forcing a hardened rounded point onto the surface as it is moved. A common method is to impinge upon the surface fine hard particles such as hardened steel spheres (shot) at high velocity. This process is called shot... 

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