Refractories high temperature

Refractories. Calcined alumina is used in the bond matrix to improve the refractoriness, high temperature strength/creep resistance, and abrasion/corrosion resistance of refractories (1,2,4,7). The normal, coarse (2 to 5 )J.m median) crystalline, nominally 100% a-Al202, calcined aluminas ground to 95% —325 mesh mesh are used to extend the particle size distribution of refractory mixes, for alumina enrichment, and for reaction with... 

Silicon is the most important constituent of igneous and many sedimentary rocks, occurring in combination with oxygen in feldspars, micas, quartz, sands and shales. The element is used in electronic devices, while silicon in combination with oxygen as silica and silicates finds application in concrete, bricks, pottery, enamels, glasses, optical fibers for telecommunications, and refractory (high-temperature resistant) materials. 

Crytal chemitry. Cubic zirconia (CZ) is a popular simulant for diamond, and deservedly so. With a Mohs hardness of 8.25 and and a refractive index of 2.15, it closely matches the scratch resistance and brilliance of authentic diamond, and its dispersion coefficient is higher (Shigley and Moses 1998). (Fortunately for those who like their gems natural, diamond and CZ are easily distinguished by density and by thermal conductivity.) Cubic zirconia also offers important technological uses as a refractory high-temperature ceramic (Meriani and Palmonari 1989). 

Fire Clay Refractories High temperature stability... 

Refractoriness High-temperature furnace linings for insulation and containment of molten metals and slags... 

The non-oxide ceramics comprise essentially borides, carbides, nitrides, and silicides. Like oxide ceramics they have two kinds of uses, which frequently overlap application of their physical properties and of their refractory high-temperature properties. Extensive accounts can be found in [2.1-3,8,10],... 

MoSij High reactability in contact with refractory High-temperature soldering by means of MoSi2 in electronics, for example cathodes of LaBg with cores of Mo, Ta, W [692] 1959... 

Alundum is used for highly refractory bricks (m.p. 2000-2100 C), crucibles, ref ractory cement and muffles also for small laboratory apparatus used at high temperatures (combustion tubes, pyrometer tubes, etc.). 

The main problem in this technique is getting the atoms into the vapour phase, bearing in mind the typically low volatility of many materials to be analysed. The method used is to spray, in a very fine mist, a liquid molecular sample containing the atom concerned into a high-temperature flame. Air mixed with coal gas, propane or acetylene, or nitrous oxide mixed with acetylene, produce flames in the temperature range 2100 K to 3200 K, the higher temperature being necessary for such refractory elements as Al, Si, V, Ti and Be. 

The fractionation of these refractory elements is beheved to be the result of relative efficiencies of incorporation of condensed sohds rich in early high temperature phases into the meteorite parent bodies at different times and locations in the solar nebula. The data are taken from Reference 3. 

Submerged-Arc Furnace. Furnaces used for smelting and for certain electrochemical operations are similar in general design to the open-arc furnace in that they are usually three-phase, have three vertical electrode columns and a shell to contain the charge, but dkect current may also be utilised They are used in the production of phosphoms, calcium carbide, ferroalloys, siUcon, other metals and compounds (17), and numerous types of high temperature refractories. 

A more extensive comparison of many potential turbine blade materials is available (67). The refractory metals and a ceramic, sHicon nitride, provide a much higher value of 100 h stress—mpture life, normalised by density, than any of the cobalt- or nickel-base aHoys. Several intermetaHics and intermetaUic matrix composites, eg, aHoyed Nb Al and MoSi —SiC composites, also show very high creep resistance at 1100°C (68). Nevertheless, the superaHoys are expected to continue to dominate high temperature aHoy technology for some time. 

At elevated temperatures, CaH2 reacts with halogens, sulfur, phosphoms, alcohols, and ammonia. At high temperatures, it reacts with refractory metal oxides and haUdes. Calcium hydride is substantially inert to organic compounds that do not contain acidic hydrogens. 

The furnace is constmcted with a steel shell lined with high temperature refractory (see Refractories). Refractory type and thickness are deterrnined by the particular need. Where combustion products include corrosive gases such as sulfur dioxide or hydrogen chloride, furnace shell temperatures are maintained above about 150—180°C to prevent condensation and corrosion on the inside carbon steel surfaces. Where corrosive gases are not present, insulation is sized to maintain a shell temperature below 60°C to protect personnel. 

Rock wool, frequently referred to as mineral fiber, is made from non virgin siUceous materials and is formed in a similar manner to that of fiber glass. Refractory fibers (qv), also formed in a similar manner, are available for high temperature appHcations. 

The cell for this process is unlike the cell for the electrolysis of aluminum which is made of carbon and also acts as the cathode. The cell for the fused-salt electrolysis is made of high temperature refractory oxide material because molten manganese readily dissolves carbon. The anode, like that for aluminum, is made of carbon. Cathode contact is made by water-cooled iron bars that are buried in the wall near the hearth of the refractory oxide cell. 

---