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Redox-dependent host-guest binding

Scheme 1.2 Equilibria involved in redox-dependent host-guest binding. Scheme 1.2 Equilibria involved in redox-dependent host-guest binding.
Oxidation of receptor 1 was found to decrease its binding affinity for alkali metal cations, due to electrostatic repulsion between 1 and the cation. Thus, the ferrocene unit not only enables redox sensing of alkali metal cations, but also allows the host guest interaction to be switched on and off depending on the oxidation state of the receptor. Saji has also demonstrated that this phenomenon can be used in electrochemical ion transport across liquid membranes. ... [Pg.467]


See other pages where Redox-dependent host-guest binding is mentioned: [Pg.147]    [Pg.1412]    [Pg.123]    [Pg.5]    [Pg.205]    [Pg.440]    [Pg.1874]    [Pg.2]    [Pg.2]    [Pg.80]    [Pg.332]    [Pg.377]   


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Binding dependency

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Host-guest

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