Reactive monitoring - reporting

Reactive monitoring arrangements inciude systems to identify and report ... 

Dutyholders should measure their performance to assess how effectively risks are being controlled. Active monitoring provides feedback on performance and a basis for learning to improve before an accident or incident, whereas reactive monitoring involves identifying and reporting on incidents to check the controls In place. Identify weaknesses and learn from failures. 

Monitoring safety management systems >- Active monitoring - tours and inspections, health surveillance or air quality sampling >- Reactive monitoring - investigating safety events, reports, etc. 

These results are consistent with recently reported results by Haller, et al. (10) on the reactions of CO/H2 and NHj over Rh catalysts In which no significant differences were observed between catalysts reduced at low and high temperatures (presumably "normal and SMSI) but In which Rh/S102 was found to behave differently. Thus, there appears to be some correlation between the FRC chemisorption results and the reactivity patterns of supported rhodium catalysts which we would like to believe supports the assertion that the sites at which hydrogen sorbs reversibly are those at which catalytlcally Important reactions occur, and that FRC can monitor the density and relative kinetics of these sites. 

Shortly after, Doetschman and Hutchison reported the first example of a reactive carbene in the crystalline solid state, by preparing diphenylcarbene from diphenyldi-azomethane in mixed crystals with 1,1-diphenylethylene 84 (Scheme 7.23). When the mixed crystals were irradiated, carbene 85 was detected by electron paramagnetic resonance (EPR) and the disappearance of the signal was monitored to determine its kinetic behavior. Two reactions were shown to take place under topochemical... 

The ability of this hydrophobic peptide environment to effect the flavin reactivity was assessed by monitoring the oxidation ofN-alkyl-l,4-dihydronicotina-mides (N-alkyl-NAH) using conditions similar to those reported in the Kaiser experiments. Under these conditions, both systems exhibited slight enhancements in the rate of oxidation of either J -benzyl-NAH or N-hexyl-NAH. Hypothesizing that the lack of performance of the system may have been due to the occlusion of the flavin from interacting with the substrate, the assays were... 

Carbohydrate detection is important for applications such as glucose monitors these are arguably one of the most successful and relevant biosensors. An interesting fluorescence recovery-type saccharide sensor based on the reactivity of carbohydrates with boronic acids was reported in 2002 [36]. Specifically, modification of the cationic viologen-linked boronic acid derivative 40 to a zwitterionic species 41 upon covalent and reversible reaction of boronic acid with monosaccharides (Scheme 1) can cause the dissociation of the ion-pair in-... 

---