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Quinolines pyrroles

For commonly encountered heterocycles, the chemical shifts of trifluo-romethyl substituents will depend somewhat upon where in the heterocycle they are located. Examples of trifluoromethyl derivatives for a number of common heterocycles, including pyridines, quinolines, pyrroles, indoles, thiophenes, benzothiophenes, furans, benzofurans, imidazoles, and uracils are given below. [Pg.178]

The work by Mills et al. (32) includes an early example of catalytic titration behavior. Figure 10 taken from their study shows that cumene cracking at 425°C drops sharply as nitrogen bases are chemisorbed in increasing amounts on silica-alumina catalyst. Base effectiveness decreases in the order quinaldine > quinoline > pyrrole > piperidine > decylamine > aniline. [Pg.114]

Nitrogen-containing constituents present are mainly pyridines, quinolines, pyrroles, and carbazoles from Yen[52]. [Pg.578]

Ban well and co-workers have converted diiodopyrrole 107 [19] to bis-boronate 108, which without purification was successfully coupled to afford bis-quinoline pyrrole 109 [74],... [Pg.51]

Synthesis of N-heterocycles (indole, quinoline, pyrrole, pyrrolizine, indo-lizine derivatives, lactams, pumiliotoxin C, and lycopodine) using Ti-activated molecular nitrogen 04JOM(689)4210. [Pg.29]

Most L-tryptophan-derived secondary products still possess the indole ring system of this amino acid. Some compounds, however, are quinoline, pyrrole or benzene derivatives. Additional rings may be present yielding complicated structures, like that of ergoline and / -carboline alkaloids (cf. the formulas of ergotamine, Corynanthe, Strychnos, Iboga and Aspidosperma-type alkaloids). [Pg.385]

Cirujano FG, Leyva-Pa"ez A, Corma A, Llabres i Xamena FX. MOFs as multifunctional catalysts synthesis of secondary arylamines, quinolines, pyrroles, and arylpyrrolidines over hifunctional MIL-101. Chem Cat Chem 2013 5 538-49. [Pg.339]

Crude oils contain nitrogen compounds in the form of basic substances such as quinoline, isoquinoline, and pyridine, or neutral materials such as pyrrole, indole, and carbazole. [Pg.326]

Although only ppm levels of nitrogen are found in the mid-distillates, both neutral and basic nitrogen compounds have been isolated and identified in fractions boiling below 345°C (12). Pyrroles and indoles account for about two-thirds of the nitrogen. The remaining nitrogen is found in the basic pyridine and quinoline compounds. Most of these compounds are alkylated. [Pg.170]

Pyridine, pyrrole, quinoline, isoquinoline and indole alkaloids Apply sample solution and place the TLC plate in an iodine vapor chamber for 18 h, remove the excess iodine in a stream of warm air. Characterization on the basis of the iodination pattern. [53]... [Pg.66]

In 1931 Ing pointed out that formula (II) and (III) do not contain methyl or potential methyl groups in j ositions 6 and 8 which they occupy in cytisoline. Further, a partially reduced quinoline ought to oxidise easily to a benzenecarboxylic acid and so far the only simple oxidation, products recorded from cytisine were ammonia, oxalic acid and isovaleric acid. Distillation of cytisine with zinc dust or soda-lime yields pyrrole and pyridine, but no quinoline. On these grounds Ing suggested that cytisine should be formulated without a quinoline nucleus, and that the reactions which indicate the presence of an aromatic nucleus in the alkaloid can be accounted for by an a-pyridone ring. This a-pyridone nucleus can... [Pg.143]

These reactions are related to the formation of pyrroles and quinolines from aminocarbonyl compounds and acetylenes (582,583) and may be contrasted with the formation of pyran derivatives by electrophilic attack on an enamine, followed by addition of an oxygen function to the imonium carbon (584-590). [Pg.437]

The idea that dichlorocarbene is an intermediate in the basic hydrolysis of chloroform is now one hundred years old. It was first suggested by Geuther in 1862 to explain the formation of carbon monoxide, in addition to formate ions, in the reaction of chloroform (and similarly, bromoform) with alkali. At the end of the last century Nef interpreted several well-known reactions involving chloroform and a base in terms of the intermediate formation of dichlorocarbene. These reactions included the ring expansion of pyrroles to pyridines and of indoles to quinolines, as well as the Hofmann carbylamine test for primary amines and the Reimer-Tiemann formylation of phenols. [Pg.58]

Pyrrole Pyridine 4- Hydroxy pyridine Indole Quinoline... [Pg.320]

Just as there are heterocyclic analogs of benzene, there are also many heterocyclic analogs of naphthalene. Among the most common are quinoline, iso-quinoline, indole, and purine. Quinoline, isoquinoline, and purine all contain pyridine-like nitrogens that are part of a double bond and contribute one electron to the aromatic it system. Indole and purine both contain pyrrole-like nitrogens that contribute two - r electrons. [Pg.533]

The chemistry of these polycyclic heterocycles is just what you miglu expect from a knowledge of the simpler heterocycles pyridine and pyrrole Quinoline and isoquinoline both have basic, pyridine-like nitrogen atoms, anc both undergo electrophilic substitutions, although less easily than benzene Reaction occurs on the benzene ring rather than on the pyridine ring, and r mixture of substitution products is obtained. [Pg.951]

Heterocyclic amines are compounds that contain one or more nitrogen atoms as part of a ring. Saturated heterocyclic amines usually have the same chemistry as their open-chain analogs, but unsaturated heterocycles such as pyrrole, imidazole, pyridine, and pyrimidine are aromatic. All four are unusually stable, and all undergo aromatic substitution on reaction with electrophiles. Pyrrole is nonbasic because its nitrogen lone-pair electrons are part of the aromatic it system. Fused-ring heterocycles such as quinoline, isoquinoline, indole, and purine are also commonly found in biological molecules. [Pg.958]

For fused heterocyclic systems too, we can often make predictions based on the above principles, though many exceptions are known. Thus, indole is chiefly substituted in the pyrrole ring (at position 3) and reacts faster than benzene, while quinoline generally reacts in the benzene ring, at the 5 and 8 positions, and slower than benzene, though faster than pyridine. [Pg.689]

Pyridine, pyrrole, indole, quinoline and isoquinoline alkaloids Silica gel G Detection by two-dimensional TLC [11]... [Pg.147]


See other pages where Quinolines pyrroles is mentioned: [Pg.591]    [Pg.1011]    [Pg.63]    [Pg.730]    [Pg.216]    [Pg.333]    [Pg.15]    [Pg.350]    [Pg.591]    [Pg.1011]    [Pg.63]    [Pg.730]    [Pg.216]    [Pg.333]    [Pg.15]    [Pg.350]    [Pg.70]    [Pg.217]    [Pg.22]    [Pg.72]    [Pg.149]    [Pg.620]    [Pg.638]    [Pg.6]    [Pg.66]    [Pg.312]    [Pg.133]    [Pg.322]    [Pg.1287]    [Pg.310]    [Pg.640]    [Pg.42]    [Pg.713]   
See also in sourсe #XX -- [ Pg.128 , Pg.179 , Pg.180 ]




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