Qualitative analysis flame photometry

Qualitative analysis-. Flame photometry is particularly useful for the determination of alkali metals and alkaline-earth metals. It provides the basis for flame tests used in qualitative analysis schemes. 

The basic instrumentation used for spectrometric measurements has already been described in the previous chapter (p. 277). Methods of excitation, monochromators and detectors used in atomic emission and absorption techniques are included in Table 8.1. Sources of radiation physically separated from the sample are required for atomic absorption, atomic fluorescence and X-ray fluorescence spectrometry (cf. molecular absorption spectrometry), whereas in flame photometry, arc/spark and plasma emission techniques, the sample is excited directly by thermal means. Diffraction gratings or prism monochromators are used for dispersion in all the techniques including X-ray fluorescence where a single crystal of appropriate lattice dimensions acts as a grating. Atomic fluorescence spectra are sufficiently simple to allow the use of an interference filter in many instances. Photomultiplier detectors are used in every technique except X-ray fluorescence where proportional counting or scintillation devices are employed. Photographic recording of a complete spectrum facilitates qualitative analysis by optical emission spectrometry, but is now rarely used. 

Analytical applications have been found for all parts of the electromagnetic spectrum ranging from microwaves through visible radiation to gamma (y) rays (Table 1). The emission and absorption of electromagnetic radiation are specific to atomic and molecular processes and provide the basis for sensitive and rapid methods of analysis. There are two general analytical approaches. In one, the sample is the source of the radiation in the other, there is an external source and the absorption or scattering of radiation by the sample is measured. Emission from the sample may be spontaneous, as in radioactive decay, or stimulated by thermal or other means, as in flame photometry and fluorimetry. Both approaches can be used to provide qualitative and quantitative information about the atoms present in, or the molecular structure of, the sample. 

Excitation of the outer ns electron of the M atom occurs easily and emission spectra are readily observed. We have aheady described the use of the sodium D-line in the emission spectrum of atomic Na for specific rotation measurements (see Section 3.8). When the salt of an alkali metal is treated with concentrated HCl (giving a volatile metal chloride) and is heated strongly in the non-luminous Bunsen flame, a characteristic flame colour is observed (Li, crimson Na, yellow K, lilac Rb, red-violet Cs, blue) and this flame test is used in qualitative analysis to identify the M ion. In quantitative analysis, use is made of the characteristic atomic spectrum in flame photometry or atomic absorption spectroscopy. 

Emission of UV/VIS radiation Flame photometry, Auger electron spectroscopy (AES) Qualitative and quantitative multielement analysis... 

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