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Quadratures

Implementation of the Kohn-Sham-LCAO procedure is quite simple we replace the standard exchange term in the HF-LCAO expression by an appropriate Vxc that will depend on the local electron density and perhaps also its gradient. The new integrals involved contain fractional powers of the electron density and cannot be evaluated analytically. There are various ways forward, all of which [Pg.226]


The variation of resistance is proportional to the amplitude of the part of the flux crossing the coil in quadrature with the current in the solenoid. [Pg.351]

The latter condition corresponds to the phase matching requirement already mentioned—the wavelength and direction of the material polarization wave must match those of the new EM wave as closely as possible. However, for all Class I spectroscopies, this condition is automatically achieved because of quadrature. In fact, this is tnie for all quadrature spectroscopies—the Class I spectroscopies being the principal such, but, as noted, it is a nontrivial requirement in the nonquadrature Class II spectroscopies, particularly in optically dispersive media. [Pg.1184]

Interestingly, tliree-coloiir spectroscopies at third order can only be of Class II, since the generators cannot possibly contain any quadrature. Maximal quadrature is necessary for Class I. [Pg.1186]

In the complex mathematical representation, quadrature means that, at the (s + 1) wave mixing level, the product of. s input fields constituting the. sth order generator and the signal field can be organized as a product of (s + l)/2 conjugately paired fields. Such a pair for field is given by = ,One sees that the exponent... [Pg.1187]

In fact, each linear polarizability itself consists of a sum of two temis, one potentially resonant and the other anti-resonant, corresponding to die two doorway events, and D, and the window events, and described above. The hyperpolarizability chosen in equation (B1.3.12) happens to belong to the generator. As noted, such tliree-coloiir generators caimot produce Class I spectroscopies (fiill quadrature with tliree colours is not possible). Only the two-colour generators are able to create the Class I Raman spectroscopies and, in any case, only two colours are nomially used for the Class II Raman spectroscopies as well. [Pg.1191]

Returning to the original pump-probe RRS, it is a simple matter to complete the 4WM WMEL diagrams for any proposed RRS. Usually RRS experiments are of the frill quadrature sort, both spontaneous RRS as well as homodyne detected femtosecond RRS. The latter fit most pump-probe configurations. [Pg.1203]

Let us, for example, present the fiill WMEL diagrams for full quadrature RRS with two colours, 1 and 2. (Recall that tliree colours caimot lead to full Q at the 4WM level.) Given the ei doorway generator for... [Pg.1203]

Clip acts in phase (the same Fourier component) with the first action of cii to produce a polarization that is anti-Stokes shifted from oi (see fV (E) and IFj (F) of figure B 1.3.2(b)). For the case of CSRS the third field action has frequency CO2 and acts in phase with the earlier action of CO2 (W (C) and IFj (D) of figure Bl.3.2 (b). Unlike the Class I spectroscopies, no fields in CARS or CSRS (or any homodyne detected Class II spectroscopies) are in quadrature at the polarization level. Since homodyne detected CRS is governed by the modulus square of hs lineshape is not a synmretric lineshape like those in the Class I... [Pg.1207]

Numerical integration methods are widely used to solve these integrals. The Gauss-Miihler method [28] is employed in all of the calculations used here. This method is a Gaussian quadrature [29] which gives exact answers for Coulomb scattering. [Pg.1810]

Tellinghuisen J A 1974 A fast quadrature method for computing diatomic RKR potential energy curves Comput. Phys. Commun. 6 221-8... [Pg.2087]

These methods, which probably deserve more attention than they have received to date, simultaneously optimize the positions of a number of points along the reaction path. The method of Elber and Karpins [91] was developed to find transition states. It fiimishes, however, an approximation to the reaction path. In this method, a number (typically 10-20) equidistant points are chosen along an approximate reaction path coimecting two stationary points a and b, and the average of their energies is minimized under the constraint that their spacing remains equal. This is obviously a numerical quadrature of the integral s f ( (.v)where... [Pg.2354]

Maurits, N.M., Altevogt, P., Evers, O.A., Fraaije, J.G.E.M. Simple numerical quadrature rules for Gaussian Chain polymer density functional calculations in 3D and implementation on parallel platforms. Comput. Theor. Polymer Sci. 6 (1996) 1-8. [Pg.36]

The integrals in Equation (3.32) are found using a quadrature over the element domain The viscoelastic constitutive equations used in the described model are hyperbolic equations and to obtain numerically stable solutions the convection terms in Equation (3.32) are weighted using streamline upwinding as (inconsistent upwinding)... [Pg.85]

Auxiliary subroutines for handling coordinate transformation between local and global systems, quadrature, convergence checking and updating of physical parameters in non-linear calculations. [Pg.196]

TOCSY data are acquired in tbe pbase-sensitive mode using quadrature detection, and aU. tbe data phases are positive. Tbis increases the SNR for the matrix, and the time required for the experiment is short because very Htde, if any, phase cycling is necessary. In some cases a single scan per FID suffices, and the data can be acquired in approximately 10 min,... [Pg.407]

The field of view (FOV) is dependent on the quadrature sampling rate, T, during the appHcation of G and the magnitude of G ... [Pg.55]


See other pages where Quadratures is mentioned: [Pg.224]    [Pg.978]    [Pg.1179]    [Pg.1179]    [Pg.1180]    [Pg.1184]    [Pg.1185]    [Pg.1186]    [Pg.1187]    [Pg.1188]    [Pg.1197]    [Pg.1197]    [Pg.1197]    [Pg.1204]    [Pg.1204]    [Pg.1208]    [Pg.1208]    [Pg.1475]    [Pg.1477]    [Pg.1574]    [Pg.1586]    [Pg.39]    [Pg.39]    [Pg.39]    [Pg.40]    [Pg.40]    [Pg.76]    [Pg.9]    [Pg.401]    [Pg.54]    [Pg.422]   
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Application of quadrature to collision terms

Computational numerical quadrature

Digital quadrature detection

Direct quadrature method of moments

Direct quadrature method of moments DQMOM)

Dual-quadrature representation

Exchange numerical quadrature techniques

Extended quadrature method of moments

Extended quadrature method of moments EQMOM)

Five-point quadrature formula

Formulas-Gauss-Legendre Quadrature

Free-energy profiles, computation polynomial quadrature method

Gauss quadrature

Gauss quadrature algorithm

Gauss quadrature points

Gauss-Chebyshev quadrature points

Gauss-Hermite quadrature

Gauss-Jacobi Quadrature

Gauss-Legendre quadrature

Gaussian quadrature abscissae

Gaussian quadrature accuracy

Gaussian quadrature algorithm

Gaussian quadrature definition

Gaussian quadrature formulas

Gaussian quadrature orthogonal functions

Gaussian quadrature orthogonal polynomials

Gaussian quadrature theory

Gaussian quadrature univariate

Gaussian quadrature weight

Gaussian quadrature weighted integrals

Gaussian quadratures

Gaussian-quadrature integration

Interpolation and Quadrature

Laguerre quadrature

Legendre quadrature

Lobatto quadrature

Moments and the quadrature approximation

Multivariate quadrature

Multivariate quadrature CQMOM

Multivariate quadrature DQMOM

Multivariate quadrature algorithm

Numerical Integration (Quadrature)

Numerical Quadrature Techniques to Handle the Exchange-Correlation Potential

Numerical integration Gaussian quadrature

Numerical quadrature

Numerical quadrature techniques

Phase cycling quadrature detection

Phase quadrature

Phase-sensitive detection (quadrature

Polynomial Quadrature Method

Quadrature 3/8 rule

Quadrature Monte Carlo integration

Quadrature Newton-Cotes integration

Quadrature aggregation

Quadrature amplitude modulation

Quadrature artifacts

Quadrature channel

Quadrature coils

Quadrature conductivity

Quadrature detection

Quadrature detection States method

Quadrature detection States-TPPI method

Quadrature detection TPPI method

Quadrature detection aliasing

Quadrature detection images

Quadrature detection methods

Quadrature detection principle

Quadrature detection using gradients

Quadrature discretization method

Quadrature formulas

Quadrature hybrid

Quadrature image

Quadrature method

Quadrature method of moments

Quadrature method of moments DQMOM

Quadrature method of moments EQMOM

Quadrature method of moments QMOM)

Quadrature mirror filter

Quadrature multidimensional integrals

Quadrature phase cycling

Quadrature phase detection

Quadrature phase-shift keying

Quadrature point coordinates

Quadrature points

Quadrature schemes

Quadrature signal

Quadrature variances

Quadrature, definition

Quadrature, solution

Quadrature-based moment methods

Quadrature-based moment methods QBMM)

Quadrature-based moment methods closure

Quadrature-based moment methods example

Quadratures Newton-Cotes

Radau and Lobatto Quadrature

Radau quadrature

Reactance Quadrature

Reactance Quadrature axis

Response quadrature

Rys - Gauss quadrature

Rys quadrature

Rys quadrature method

Rys quadrature scheme

Simpsons Quadrature Formula

Spectrum quadrature

Standard quadrature grid

Summing in quadrature

Surface Quadrature

The direct quadrature method of moments (DQMOM)

The direct quadrature method of moments fully conservative

The extended quadrature method of moments (EQMOM)

The standard quadrature grid

Two-Point Gauss-Legendre Quadrature

Univariate quadrature

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