Processing, thermoplastics flat film

The analysis indicates that presently quite adequate phenomenological models are available for description of the straining of commercial (polydisperse) polymers in the liquid state. A comparatively clear understanding of the mechanics of the processes of manufacturing of sleeve-type and flat films of molten thermoplastics also has been developed. So far, physical approaches have provided rheological models only for monodisperse polymers (the properties of which differ significantly from those of the ones used in industry). 

Several liquid cryatalline polymers were melt blended with an amorphous (Ultem) and two semicrystalline (PEEK and PPS) engineering thermoplastics in a single screw extruder. Flat film was processed with different degrees of stretch imparted while the film was being cooled. In the case of Vectra, which was thought to be ideally suited to be blended with PPS based on thermal and rheological... 

Polyester. Poly(ethylene terephthalate) [25038-59-9] (PET) polyester film has intermediate gas- and water- vapor barrier properties, very high tensile and impact strengths, and high temperature resistance (see Polyesters, thermoplastic). AppHcations include use as an outer web in laminations to protect aluminum foil. It is coated with PVDC to function as the flat or sealing web for vacuum/gas flush packaged processed meat, cheese, or fresh pasta. 

Free mono- and multilayer films may be adhesive- or extmsion-bonded in the laminating process. The bonding adhesive may be water- or solvent-based. Alternatively, a temperature-dependent polymer-based adhesive without solvent may be heated and set by cooling. In extmsion lamination, a film of a thermoplastic such as polyethylene is extmded as a bond between the two flat materials, which are brought together between a chilled and backup roU. 

Prokunin, Sevruk, and Fridman 37,68,69) have suggested an additional characteristic of rheological and technological properties of thermoplastics used as raw materials in such processes where an important stage is the longitudinal deformation of melts, for example, to produce films, fibers, flat threads, thermal drawing of sheet blanks, etc. 

PBS is a typical thermoplastic and can be processed via various methods, such as extrusion, injection molding, film blowing, fiber spinning, and thermoforming. It has been reported that PBS can be processed into melt-blown, multifilament, monofilament, nonwoven, flat and split yarn, injection-molded products, film, paper laminate, sheet, and tape for applications in the textile and plastic industries. 

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