Preparations and Reactions of Oxide

Preparations and reactions of oxide fluorides of the transition metals, the lanthanides and the actinides. J. H. Holloway and D. Laycock, Adv. Inorg. Chem. Radiochem., 1984, 28, 73 (278). 

PREPARATIONS AND REACTIONS OF OXIDE FLUORIDES OF THE TRANSITION METALS, THE LANTHANIDES, AND THE ACTINIDES... 

Preparations and Reactions of Oxide Fluorides of the Transition Metals, the Lanthanides, and the Actinides John H. Holloway and David Laycock... 

Contents Introduction and Principles. - The Reaction of Dichlorocarbene With Olefins. - Reactions of Dichlorocarbene With Non-Olefinic Substrates. -Dibromocarbene and Other Carbenes. - Synthesis of Ethers. - Synthesis of Esters. - Reactions of Cyanide Ion. - Reactions of Superoxide Ions. - Reactions of Other Nucleophiles. - Alkylation Reactions. - Oxidation Reactions. - Reduction Techniques. - Preparation and Reactions of Sulfur Containing Substrates. -Ylids. - Altered Reactivity. - Addendum Recent Developments in Phase Transfer Catalysis. 

H. W. Arnold and W, L. Bvans, The mechanism of carbohydrate oxidation. Fait XXB. The preparation and reactions of glyceraldehyde diethyl mereaptal, J. Am. Chan. Soc. 58 1950... 

PREPARATIONS AND REACTIONS OF INORGANIC MAIN-GROUP OXIDE FLUORIDES... 

The preparation and reaction of 1-alkylthioisoquinolinium salts with active methylene compounds was studied <02CPB225>. The selective N- and O-alkylation of 1-isoquinolones using Mitsunobu conditions was also studied <02JCS(P1)335>. Additionally, the oxidation of isoquinoline derivatives to the corresponding isoquinolones using iodosobenzene and catalytic tetrabuty(ammonium iodide was reported <02HCA1069>. 

The physical properties, preparation and reactions of ruthenium tetroxide have been reviewed by Lee and van den Engh, Rylander," Haines and Hetuy and Lange. A more vigorous oxidant than osmium tetroxide, its reaction with double bonds produces only cleavage products. " Under neutral conditions aldehydes are formed from unsaturated secondary carbons while carboxylic acids are obtained under alkaline or acidic conditions. For example, Shalon and Elliott" found that ruthenium tetroxide reacted with compound (11) to give the corresponding aldehyde under neutral conditions, but that a carboxylic acid was formed in acidic or alkaline solvents (equation 23). 

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