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Power measurements considerations, general

It is known that incompressible newtonian fluids at constant temperature can be characterized by two material constants the density p and the viscosity T. The characterization of a purely viscous nonnewtonian fluid using the power law model (or any of the so-called generalized newtonian models) is relatively straightforward. However, the experimental description of an incompressible viscoelastic nonnewtonian fluid is more complicated. Although the density can be measured, the appropriate expression for r poses considerable difficulty. Furthermore there is some uncertainty as to what other properties need to be measured. In general, for viscoelastic fluids it is known that the viscosity is not constant but depends on shear rate, that the normal stress differences are finite and depend on shear rate, and that the stress may also depend on the preshear history. To characterize a nonnewtonian fluid, it is necessary to measure the material functions (apparent viscosity, normal stress differences, etc.) in a relatively simple or standard flow. Standard flow patterns used in characterizing nonnewtonian fluids are the simple shear flow and shear-free flow. [Pg.734]

N,N-dibenzylamino)ethyl 2-, 3-, and 4-benzoylbenzoate. The first fluorescence and fluorescence quantum yield measurements from the excited state of the radical anion of benzo-l,4-quinone have appeared, and since these species are powerful reducing agents generally, such parameters are of considerable impor-... [Pg.189]

The basic experimental arrangements for photocurrent measurements under periodic square and sinusoidal light perturbation are schematically depicted in Fig. 19. In the previous section, we have already discussed experimental results based on chopped light and lock-in detection. This approach is particularly useful for measurement at a single frequency, generally above 5 Hz. At lower frequencies the performance of lock-in amplifier and mechanical choppers diminishes considerably. For rather slow dynamics, DC photocurrent transients employing optical shutters are more advisable. On the other hand, for kinetic studies of the various reaction steps under illumination, intensity modulated photocurrent spectroscopy (IMPS) has proved to be a very powerful approach [132,133,148-156]. For IMPS, the applied potential is kept constant and the light intensity is sinusoid-... [Pg.221]

Equation 6.44 gives the total power emitted by a black body. However, materials and bodies whose temperatures are measured with radiation-type instruments often deviate considerably from ideal black body behaviour. This deviation is expressed generally in terms of the emissivity e of the measured body (see also Volume 1, Section 9.5.4), and the energy emitted by the body per unit area per unit time is ... [Pg.475]

Selection of a health outcome for study depends in part upon the exposure of interest and methodological considerations such as the ability to define, measure, and validate adverse outcomes, especially if self-reported. Operational definitions for outcomes can be general or specific in nature (e.g., all birth defects versus spina bifida, respectively), and will affect the type of statistical analysis which can be performed and the interpretation of results. Statistical power may be limited if restrictive operational definitions are used for rare outcomes, or if other important covariates cannot be fully addressed. [Pg.75]


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General considerations

Power, measurement

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