Potassium nickel ferricyanide

Potassium nickel ferricyanide [potassium nickel hexakis(cyano-ferrate(3-))] KNi[Fe(CN)6] [53295-14-0]... 

Reduction to S(IV) is the basis of two spot tests of Feigl, although these apply to other S(VI) classes, e.g. sulphonamides. Thus Feigl and Lenzer fused the sample with alkali to yield sulphite, then treating with hydrochloric acid and warming to expel sulphur dioxide they detected the latter with nickel(II) hydroxide on test paper, which yielded ultimately the black Ni(IV) oxyhydrate (see also Section C). In the other test FeigF fused the sample with sodium formate/alkali, cooled and acidified with sulphuric acid to liberate sulphur dioxide in this case also. This was detected by a ferric chloride/potassium ferricyanide reagent which yielded a blue colour (Prussian, Turnbull s). 

Cyanide occurs most commonly as hydrogen cyanide in water, although it can also occur as the cyanide ion, alkali and alkaline earth metal cyanides (potassium cyanide, sodium cyanide, calcium cyanide), relatively stable metallocyanide complexes (ferricyanide complex [Fe(CN)6]-3), moderately stable metallocyanide complexes (complex nickel and copper cyanide), or easily decomposable metallocyanide complexes (zinc cyanide [Zn(CN)2], cadmium cyanide [Cd(CN)2]). Hydrogen cyanide and cyanide ion combined are commonly termed free cyanide. The environmental fate of these cyanide compounds varies widely (Callahan et al. 1979). 

Methyl orange III, P. 23 Nickel chloride XI Nitric acid, 6mormal Nitric acid, 16-normal Phenolphthalein P. 53 Phosphoric acid, ortho, 85% IV Potassium chlorate (chloride free) III Potassium ferricyanide III, IX, P. 73, Q. 73... 

The synthesis of bufotenine itself followed closely upon the proof of its structure. Hoshino and Shimodaira reduced the ethyl ester of 5-ethoxy-indole-3-acetic acid by the Bouveault-Blanc procedure to the corresponding primary alcohol, which was treated with phosphorus tribromide and then dimethylamine, to give the ethyl ether of bufotenine, which was demethylated with aluminum chloride (130). In a later synthesis, 2,5-dimethoxybenzyl cyanide (XXIII) was alkylated by Eisleb s method with dimethylaminoethyl chloride in the presence of sodamide to give l-(2,5-dimethoxyphenyl)-3-dimethylaminopropyl cyanide (XXIV), which was then hydrogenated over Haney nickel to yield 2-(2,5-di-methoxyphenyl)-4-dimethylaminobutylamine (XXV R = Me). De-methylation of this with hydrobromic acid, followed by oxidation of the product (XXV R = H) with potassium ferricyanide yielded bufotenine (XIX) via the related quinone (109). 

More intensive dehydrogenation of primary amines having two hydrogen atoms on the adjacent carbons leads to nitriles. Such dehydrogenations are accomplished by argentic oxide cobalt peroxide [1136], nickel peroxide [936], lead tetraacetate [443, 444], sodium hypochlorite [692], potassium ferricyanide [924], and potassium ruthenate [196] (equation 513). 

Gas chromatographic methods measure the carbon monoxide content of blood. Y/hen blood is treated with potassium ferricyanide, carboxyhemoglobin is converted to methemoglobin, and the carbon monoxide is released into the gas phase. Measurement of the released carbon monoxide may be performed by GC using a molecular sieve column and a thermal conductivity detector. A lower detection limit is achieved by incorporating a reducing catalyst (e.g., nickel) between the GC column and the detector to convert... 

In the separation of caesium, the following inorganic cation exchangers are particularly useful potassium cobalt(II) hexacyanoferrate(II) [12,13], potassium copper(II) and nickel(II) hexacyanoferrates(II) [14], ammonium molybdophosphate [13,15], zirconium molybdoarsenate [16], thallium tungstophosphate [17], and tin molybdosilicate [18]. Rubidium has been selectively isolated on columns filled with titanium tungstoarsenate [19] or titanium ferricyanide [20]. Ammonium molybdoarsenate has been used to separate potassium from sodium [21]. 

Pores and active defects in nonmetallic coatings can be revealed by color indication or deposit fomation. On nickel substrates, dimethylglyoxime, or steel, potassium ferricyanide (ferroxyl test) indicator can be applied to surface on filter paper while substrate is made the anode. Alternatively, a substrate immersed in acidic copper sulfate can be made the cathode to form copper nodules at conductive coatings defects. 

DEKTAL DEVELOPER KODAK FIXER KODAK SHORT STOP POTASSIUM ALUM POTASSIUM BICARBONATE POTASSIUM BICHROMATE POTASSIUM BORATE POTASSIUM BROMATE POTASSIUM BROMIDE POTASSIUM CARBONATE POTASSIUM CHROMATE POTASSIUM CHLORATE POTASSIUM CHLORIDE POTASSIUM CYANIDE POTASSIUM DICHROMATE POTASSIUM FERRICYANIDE POTASSIUM FERROCYANIDE POTASSIUM FLUORIDE POTASSIUM HYDROXIDE POTASSIUM NITRATE POTASSIUM PERBORATE POTASSIUM PERCHLORATE POTASSIUM PERMANGANATE. 10% POTASSIUM SULFATE PROPANE PROPANE GAS PLATING SOLUTIONS BRASS CADMIUM COPPER GOLD INDIUM LEAD NICKEL RHODIUM SILVER TIN ZINC... 

---