Positron life-times

Dutta S, Chattopadhyay S, Jana D, Banerjee A, Manic S, Pradhan S K, Sutradhar M, SarkarA, Annealing effect on nano ZnO powder studied from positron life time and optical absorption spectroscopy, J. Appl. Phys., 100, 114328-6, 2006. 

TEMPERATURE DEPENDENCE OF POSITRON LIFE-TIMES IN N-OCTANE AND N-HEXADECANE. 

The flow distribution in a model soil column (length 1 m, diameter 10 cm) with defined disturbing inserts (Fig. 2.1) was studied to demonstrate the feasibility of PET-studies. The measurements were carried out with a commercial PET-camera (Siemens ECAT EXACT HR (3D)). Kaliumfluoride, marked with the positron emitting isotope F-18 (half life time 110 min), was applied as hydrodynamic tracer. Fluorides of two-valent cations are only slightly soluble. The radio tracer would be absorbed in the col-... 

Positron Annihilation Life Time Spectroscopy (PALS) and Free Yolnme... 

The life-times of positrons in a solid depend upon the particular mechanism of annihilation (e.g. through formation of positronium or positron-ion combinations). Consequently, measurements of positron annihilation rates give results which again may be interpreted in terms of electronic structure. 

A final, highly specialized procedure for monitoring carbon flow in plants involves the use of "CO . The use of this positron gamma-emitting isotope of C, with a half-life of 20.3 min, allowed several physiological parameters of my-corrhizal and non-mycorrhizal plants of Panicum coloratum to be measured simultaneously in real time (82). However, the technical problems associated with using "COi, particularly the ability to produce i.sotopes of carbon, and with handling this short half-life are likely to limit this approach to specialised facilities. 

Radioactivity is the spontaneous emission of radiation from an unstable nucleus. Alpha (a) radiation consists of helium nuclei, small particles containing two protons and two neutrons (fHe). Beta (p) radiation consists of electrons ( e), and gamma (y) radiation consists of high-energy photons that have no mass. Positron emission is the conversion of a proton in the nucleus into a neutron plus an ejected positron, e or /3+, a particle that has the same mass as an electron but an opposite charge. Electron capture is the capture of an inner-shell electron by a proton in the nucleus. The process is accompanied by the emission of y rays and results in the conversion of a proton in the nucleus into a neutron. Every element in the periodic table has at least one radioactive isotope, or radioisotope. Radioactive decay is characterized kinetically by a first-order decay constant and by a half-life, h/2, the time required for the... 

The very short reaction times required for the alkylation of substrate 11a with benzylic bromides using Nobin as an asymmetric phase-transfer catalyst are important for the synthesis of 18F-fluorinated amino adds for use in positron-emission tomography (PET)-imaging studies. Thus, Krasikova and Belokon have developed a synthesis of 2-[18F]fluoro-L-tyrosine and 6-[18F]fluoro-L-Dopa employing a (S)-Nobin-catalyzed asymmetric alkylation of glycine derivative 11a as the key step, as shown in Scheme 8.14 [29]. The entire synthesis (induding semi-preparative HPLC purification) could be completed in 110 to 120 min, which corresponds to one half-life of18 F. Both the chemical and enantiomeric purity of the final amino acids were found to be suitable for clinical use. 

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