Polymers metal-containing conjugated

Moorlag, C., B.C. Sih, T.L. Stott, and M.O. Wolf 2005. Metal-containing conjugated materials Oligomers, polymers, and nanomaterials. J Mater Chem 15 2433-2436. 

K. Y. K. Man, H. L. Wong, W. K. Chan, C. Y. Kwong, A. B. Djurisic, Efficient photodetectors fabricated from a metal-containing conjugated polymer by a multilayer deposition process, Chemistry of Materials 2004, 16, 365. 

Figure 5.1 Classification of metal-containing conjugated polymers...

MSOL71R O. Lavastre, M. Even, C. Troccon, P. H. Dixneuf, A. Pacreau, and J. P. Vairon, Macromol. Symp., 1997, 122, 71-76. Organometallic Reactions as Tools to Build New Metal-Containing Conjugated Polymers. IV... 

Metal-containing conjugated polymers have been prepared, but there have been very few optical measurements. Palladium poly-ynes with a molecular weight of 32 000 have been loaded into polyimide, and power-limiting and direct ri2 measurements made [134] (Fig. 4.23). 

Liu B, Yu W-L, Pei J, Liu S-Y, Lai Y-H, Huang W (2001) Design and synthesis of bipyridyl-containing conjugated polymers effects of polymer rigidity on metal ion sensing. Macromolecules 34 7932-7940... 

In this review, well-defined metal-containing PAEs are described whose primary structure is represented by one of the schematic drawings A-C and E shown in Fig. 2. In contrast to the structures shown in the A-C systems, E has a conjugated phenyleneethynylene with metal chelates as end groups. PAEs containing metal complex as side groups (D) have, up to now, not been described in the literature. The classes of compounds such as metal-bridged alkynes, the poly(metallayne)s, and polymer carbyne complexes (structures G and H) do not in fact represent PAEs. 

Metal-containing polymers, in which the metal is coordinated to the polymer chain, are interesting from the standpoint that the conjugated backbone can help stabilize redox activity, affording a continuum of accessible states. The very nature of these materials suggests an array of potential uses (e.g., electro-catalysis, electrochromic displays, and molecular recognition). There are many ex-... 

Despite the extensive application of ruthenium complexes in DSSC, transition metal containing polymers have received relatively little attention in the fabrication of polymeric photovoltaic cells. Most of the early works on ruthenium containing polymers were focused on the light-emitting properties.58-60 Several examples of ruthenium terpyridine/bipyridine containing conjugated polymers and their photoconducting/electroluminescent properties were reported.61,62... 

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