Bulk polymer density

Entry Ti/Mg Ratio Catalyst Efficiency (g PE/g catalyst) Polymer Bulk Density (g/cm3) Melt Index (g/10 min)... 

Ti/Mg Catalyst Efficiency Polymer Bulk Density Melt Index... 

Van Krevelen [20] examined various equations for solution viscosity. He recommended the use of the following two equations [24,25] for the r ss of dilute polymer solutions (at polymer concentrations above the limit of c—>0 but with low values of c, especially c<0.01 g/cc). In these equations, Solv denotes the solvated volume fraction (see Section l.D for conversions between volume, weight and mole fractions) of the polymer, and p is the polymer bulk density. 

The quotient (r /r o), which indicates the magnitude of shear thinning effect with increasing y, can be estimated quite well as a function of the Weissenberg number (Nwg) and the polydispersity [7], N yg is the product of a characteristic time scale for the polymer with y, and can be approximated by Equation 13.27 where p is the polymer bulk density at the temperature of calculation. (The density must be expressed in g/m3 rather than g/cc in Equation 13.27 for consistency with the units used for the other quantities entering this equation.) Since the polydispersity Mw/Mn enters Equation 13.27, r depends on the polydispersity both indirectly via the dependence of Ny/g on Mw/Mn and directly. 

Calculate the Weissenberg number N yg at the shear rate of interest via Equation 13.27, with the value of the polymer bulk density estimated by using the equations given in Chapter 3. 

In some cases a greater range of alkylaluminums can be used. Al(i-Bu)3 is not a useful cocatalyst for Cp2TiCl2 but functions more effectively when the titanocene is supported on MgCl2, with a catalyst activity of 142 kg/g Ti and polymer bulk density of... 

One unusual but nevertheless important application of SAN has been in the manufacture of polymer polyols used in the manufacture of flexible polyurethane foams. Proportions of up to 40% of the polyol may be used to increase stiffness as foam bulk densities are lowered (see Section 27.5.4). 

In the 1990s this approach became more common in order to ensure sufficient compressive strength with the trend to lower bulk densities. Furthermore the proportion of SAN to polyol has been increased to about 40%. This may lead to serious stability problems and care must be taken to control the size and distribution of the particles and prevent agglomeration. Polymer polyols using polystyrene as the polymer component have recently become available (Postech-Shell) and are claimed to exhibit good stability, low viscosity and less discolouration as well as providing price advantages. 

A MC study of adsorption of living polymers [28] at hard walls has been carried out in a grand canonical ensemble for semiflexible o- 0 polymer chains and adsorbing interaction e < 0 at the walls of a box of size C. A number of thermodynamic quantities, such as internal energy (per lattice site) U, bulk density (f), surface coverage (the fraction of the wall that is directly covered with segments) 9, specific heat C = C /[k T ]) U ) — U) ), bulk isothermal compressibility... 

FIG. 20 (a) Density profiles p(z) vs z for e = —2 and four average bulk densities (f> as indicated, (b) Surface excess vs density in the bulk for four choices of e. (c) Profiles for the diagonal components of the pressure tensor and of the total pressure for (p = l.O and e = —2. Insert in (c) shows the difference between P, and Px to show that isotropic behavior in the bulk of the film is nicely obtained, (d) Interfacial tension between the polymer film and the repulsive wall vs bulk density for all four choices of e. Curve is only a guide for the eye [18]. 

The Vinyloop process is based on the selective dissolution of PVC used in composites applications like cable insulation, flooring, tarpaulins, blisters, etc. After removal of insoluble parts like metals, rubber or other polymers, the PVC is reprecipitated with all additives by introduction of a non-solvent component whieh will form with the seleetive solvent an azeotropie mixture. By using typical conditions, the process is able to reeover a pure PVC eompound powder ready for use without any additional treatment like melt filtration or a new pelletisation (speeific characteristics of the powder are average diameter of 400 microns and bulk density above 600 kg/ eub.m). All the solvents used are eompletely reeyeled and reused. PVC compounds recovered in the Vinyloop process can be reused in a closed-loop recycling scheme... 

The simple catalyst embedding technique has been applied to ethylene polymcaization in slurry In this technique, active catalytic components are embedded into styrene polymer matrix. The resulting polyethylene shows better morphology and higher bulk density than those produced by homogeneous catalyst. No activity loss was also observed with the... 

A suitable approach to the equilibration of an amorphous polymer system at bulk density becomes much more likely when the fully atomistic model in continuous space is replaced by an equivalent coarse-grained model on a lattice with sufficient conformational flexibility. Different strategies, which seek results at different levels of detail, can be employed to create an appropriate coarse-grained model. Section 4 (Doruker, Mattice) describes an approach which attempts to retain a connection with the covalent bonds in the polymer. The rotational isomeric state (RIS) [35,36] model for the chain is mapped into... 

Smith, N. M. and Parnaby, ]., Bulk Density Versus Hydrostatic Pressure Characteristics of Plastics in Powder and Pellet Form, Polym. Eng. Sci., 20, 830 (1980)... 

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