Poly , mesoscopic

A similar approach, in spirit, has been proposed [212] for the study of two-component classical systems, for example poly electrolytes, which consist of mesoscopic, highly-charged, poly ions, and microscopic. 

The bilayer morphology of thin asymmetric films of may be unstable. A regularly corrugated surface structure of the films was ascribed to spinodal transition into a laterally phase separated structure, where the surface morphology depended on the polymer incompatibility and the interfacial interactions [347, 348]. Recently, the phase separation and dewetting of thin films of a weakly incompatible blend of deuterated PS and poly(p-methylstyrene) have been monitored by SFM [349, 350]. Starting from a bilayer structure, after 454 h at T= 154 °C the film came to the final dewetting state where mesoscopic drops of... 

Aida and coworkers developed poly(pyrrole)-containing mesoporous silica films in both hexagonal and lamellar phases.34 The polypyrrole chains are highly constrained and insulated when incorporated within hexagonal mesoscopic channels and the possibility of the polarons recombining into bipolarons is significantly suppressed. In contrast, the two-dimensional lamellar phase affords spatial freedom for electron recombination. 

BeKsto S, Bartucci R, Montesano G, Marsh D, SporteUi L (2000) Molecular and mesoscopic properties of hydrophilic polymer-grafted phospholipids mixed with phosphatidylcholine in aqueous dispersion interaction of dipalmi-toyl N-poly(ethylene glycol) phosphatidyleth-anolaminewithdipalmitoylphosphatidylcholine studied by spectrophotometry and spin-label electron spin. Biophys J 78 1420-1430... 

Poly(3-decylthiophene) in crystalline powders has a co-planar structure, but the alkyl-chain planes are not co-planar with the thiophene backbone [89]. This polymer shows a temperature-dependent polymorphism with two crystalline and a (probably nematic) mesoscopic phase [90]. In the mesoscopic phase the side-chains can freely rotate, while the main chains can deviate from planarity. 

Eslami, H., Grmela, M., and Bousmina, M., A mesoscopic rheological model of poly-mer/layered silicate nanocomposites, J. Rheol., 51,1189-1222 (2007). 

Spyriouni, T., and Vergelati, C. 2001. A molecular modeling study of binary blend compatibility of polyamide 6 and poly(vinyl acetate) with different degrees of hydrolysis An atomistic and mesoscopic approach. Macromolecules 34 5306-5316. 

Erdogan, B., J.N. Wilson, and U.H.F. Bunz. 2002. Synthesis and mesoscopic order of a sugar-coated poly(p-phenyleneethynylene). Macromolecules 35 7863. 

Kanaya T, Takeshita H, Nishikoji Y, Ohkxira M, Nishida K, Kaji K (1998) Mioo- and mesoscopic stmctme of poly(vinyl alcohol) gels determined by neutron and light scattraing. Supramol Sci 5 215... 

Figure 9.26 Scanning electron micrograph from a 25/75 poly(methyl methacrylate)/MAM foam produced at 30 MPa and 60°C showing a mesoscopic structuration.

Application DPD Simulation in Multiscale. DPD simulation method in multiscale i.e. parameter derived from atomistic simulations has been successfully implemented for different real polymeric systems. The mesoscopic morphology of linear and graft- fluorinated block copolymers has been investigated by Ozan et al. Polyethylene and poly (L-lactide) polymer blends and di-block copolymers have been investigated as a function of chain... 

Soto-Figueroa C, Vicente L, Martinez-Magadan JM, Rodriguez-Hidalgo MD. Self-organization process of ordered structures in linear and star poly(styrene)-poly(isoprene) block copolymers Gaussian models and mesoscopic parameters of polymeric systems. J Phys ChemB 2007 11 11756. 

Komarov, P. V., Veselov, 1. N., and Khalatur, P. G. Nanoscale morphology in ionic membranes on the basis of sulfonated aromatic poly(ether ketones) Mesoscopic simulation. Vysokomol. Soed, 52A(2), 279-297 (2010). 

---