Poly film atom transfer radical

As an illustration of the application of these techniques, the surface of poly(ethylene terephthalate) (PET) films has been modified via the grafting of polyacrylamide (PAM) by surface-initiated atom transfer radical polymerization (ATRP) and UV-initiated grafting in order to obtain a film of PET with a hydrophilic surface [15c],... 

Lao HK, Renard E, ElFagni A, Langlois V, VaUee-Rehel K, Linossier I. Functionalization of Poly(3-hydroxybntyrate-co-3-hydroxyvalerate) Films via surface-initiated atom transfer radical polymerization Comparison with the conventional free-radical grafting procedure. J Appl Polym Sci 2011 120 184—194. 

Hikita, M., Tanaka, K., Nakamura, T. et al. (2004) Aggregation states and surface wettability in films of poly(styrene-block-perfluorooctyl ethyl acrylate) diblock copolymers synthesized by atom transfer radical polymerization. 

Chloromethylated polystyrene and chloromethylated poly(a-methyIstyrene) are negative type resists having high sensitivity and high resolution. In the pulse radiolysis of solid films of this polymer, the absorption spectra of substituted benzyl-type polymer-radical and the charge transfer complex between phenyl rings and chlorine atoms were observed (Fig. 17) [59], The benzyl-type radical may be produced by the dissociative electron attachment to the benzyl part of chloromethylated polystyrene (CMS). 

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