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Plugging Nanomaterials into Proteins - Carbon Nanotubes

Plugging Nanomaterials into Proteins - Carbon Nanotubes [Pg.29]

Work on the nanostructuring of electrodes with carbon nanotubes by Gooding and coworkers [96, 97] has demonstrated that superior electrochemical performance can be achieved with carbon nanotubes that are vertically aligned compared with being [Pg.29]

The rate constants for electron transfer achieved by plugging the nanotubes into the proteins as described above are an order of magnitude or more greater than those reported by Guiseppi-Elie et al. [92] and Zhao ef al. [95] when interfacing wild-type [Pg.30]

The fast rate constant for electron transfer was attributed to the small size of the single-walled carbon nanotubes employed (typically only 1 nm in diameter [94]). It is noteworthy that an almost identical rate constant was reported by Zhao et al. [95] using nanotube-modified electrodes prepared in a very similar way. [Pg.29]


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