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Tris triethylphosphine platinum

Tris(triethylphosphine)platinum was originally prepared by vacuum thermolysis... [Pg.107]

The properties of tris(triethylphosphine)platinum(0) are described with those of tris(triisopropylphosphine)platinum(0). [Pg.108]

Tris(triethylphosphine)Pt(0) reacts with various halodisilanes to give bis(orga-nosilyl)platinum(O) complexes 24 in high yields (Eq. 8) [22]. In the case of the reaction with iodopentamethyldisilane, however, oxidative addition of the Si-I bond onto the Pt(0) complex takes place exclusively. [Pg.136]

The platinum complex formed in the reaction between C6(CF3)6 and tris(triethylphosphine)platinum shows only a single band at 30°C [5 -51-2, y(P-CFj) 3-0, /(Pt-CFj) 27-5 Hz], which must result from fluxional behaviour in solution, since X-ray crystallography shows the structure of the solid to be as in [370], with alternate long and short bonds in the non-planar C6 ring. (159, 160) At — 90°C the spectrum... [Pg.110]

Tris(triethylphosphine)platinum was originally prepared by vacuum thermolysis of Pt(PEt3)4, but the latter was synthesized from Pt(B3H7XPEt3)2, which is an inconvenient starting material. A direct synthesis from readily available starting materials is the reaction of K2[PtCl with KOH and PEt3 in alcohol, but the product is difficult to isolate from the reaction mixture in pure form. The procedure described here is based on the vacuum thermolysis of Pt(PEt3)4, as obtained by a procedure outlined in this volume. ... [Pg.119]

Poraij-Koshits MA (1978) Structural effects of mutual influence of ligands in transition- and non-transition-metal complexes. Koordinatsionnaya Khimiya 4 842-866 (in Russian) Hartley FR (1973) The cis- and trans-effects of ligands. Chem SocRev 2 163-179 Russell DR, Mazid MA, Tucker PA (1980) Crystal structures of hydrido-tris(triethyl-phosphine)platinum(II), fluoro-tris(triethylphosphine)platinum(lD, and chloro-tris(trieth-ylphosphine)platinum(II) salts. J Chem Soc Dalton Trans 1737-1742 Blau R, Espenson J (1986) Correlations of platinum-195-phosphorus-31 coupling constants with platinum-hgand and platinum-platinum bond lengths. Inotg Chem 25 878-880 Belsky VK, Konovalov 1, Kukushkin VYu (1991) Structure of cis-dichloro-(dimethyl-sulfoxide)-(pyridine)platinum(II). Acta Cryst C47 292-294... [Pg.225]

Cl8H4 sBClFftPaPt, Chloro tris(triethylphosphine)platinum(II) tetra-fluoroborate, 46B, 1258... [Pg.624]

BP2PtC44H63, Platinum(ll), (ii -cyclooc-tenyl)bis(triethylphosphine)-, tetra-phenylborate(l -), 26 139 BP4PtC34H33, Platinum(ll), p-hydrido-hydri-dophenyltetrakis(triethylphosphine)-di-, tetraphenylborate(l —), 26 136 B2F H7lr3PsC7 H72, Iridium(2-I-), tris[l,2-ethanediylbis(diphenylphosphine)]-heptahydridotri-, bis[tetraf1uoroborate-(1-)1, 27 25... [Pg.375]

PtP4C24H8 , Platinum(O), tetrakis(triethyl-phosphine)-, 28 122 PtP4C,2H8o, Platinum(O), tetrakis(tri-phenylphosphine)-, 28 124 Pt2BH3P4C4,H8o, Platinum(II), di-p-hydrido-hydridotetrakis(triethylphosphine)di-, tetraphenylborate( I -), 27 34... [Pg.413]

SClFjOjPtCijHjo, Platinum(II), chloro-bis(triethylphosphine)(trifluoro-methanesulfonato)-, cis-, 26 126, 28 27 SClNOjPCijHij, Sulfamoyl chloride, (tri-phenylphosphoranylidene)-, 29 27 SCI2OSP3C55H4S, Osmium(II), dichloro(thio-carbonyl)tris(triphenylphosphine)-, 26 185... [Pg.418]

PrCl2Li02Si4C3oH,g, Praseodymium, bis[q -1,3-bis(trimethylsilyl)-cyclopentadienyl]di- -chloro-bis(tetrahydrofuran)lithium-, 27 170 PrOjCgsHgj, Praseodymium, tris(2,6Kli tert-butyl-4-methylphenoxoK 22 167 Pr2Cl2Si4C44H 4, Praseodymium, tetrakis-[if -l,3-bis(trimethylsilyl)-cyclopentadienyl]di-/t-chloro-di-, 27 171 PtAu2CIFj03P4SC4,Hjo. Platinum(l-l-), chloro-1 -kC lbis(triethylphosphine-... [Pg.450]

Bis(trichlorostannyl)bis(triethylphosphine)platinum, Sn-00261 Bis(trichlorostannyl)dichloroplatinate(2-), see Sn-00477 Bis(trichlorotin)bis(triethylphosphine)platinum, see Sn-00261 Bis(/i43-trichlorotin)tris( 1,5-cyclooctadiene)triplatinum, see Sn-00390... [Pg.138]

C20H3yClINPjPt, trans-Iodo(p-chloropheny1-methylisocyanide)bis(tri-ethylphosphine)platinum(II), 40B, 710 C20H37N20P2RhS2, Butanoylbis(triethylphosphine)(maleonitriledithio-lato)rhodium(III), 45B, 864... [Pg.396]

See other pages where Tris triethylphosphine platinum is mentioned: [Pg.108]    [Pg.1160]    [Pg.6033]    [Pg.706]    [Pg.357]    [Pg.120]    [Pg.430]    [Pg.437]    [Pg.390]    [Pg.104]    [Pg.291]    [Pg.417]    [Pg.422]    [Pg.141]    [Pg.342]    [Pg.368]    [Pg.390]    [Pg.391]    [Pg.417]    [Pg.1036]    [Pg.406]    [Pg.417]    [Pg.422]    [Pg.431]    [Pg.448]    [Pg.401]    [Pg.407]    [Pg.430]   
See also in sourсe #XX -- [ Pg.19 , Pg.108 ]



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