Phyllosilicates groups

Table 1.3. Phyllosilicate groups commonly found in clay fractions of soils ...

F. J.V.E. and Airoldi, C.A. (2006) Some features associated with organosilane groups grafted by the sol-gel process onto synthetic talc-like phyllosilicate. Journal of Colloid and Interface Science, 297, 95-103. 

Extremely high ion exchange affinities are however sometimes observed for alkali metals (e.g. Cs) and transition metal ion complexes in clay minerals and zeolites. The objective of this paper is to give an account of the factors which are involved in these high selectivity phenomena. The discussion will be focussed mostly on montmorillonites and faujasites as representatives of the phyllosilicate and tectosilicate groups. 

In a limestone deposit at Kinnekulle, Sweden, a remarkable collection of more than 40 highly altered meteorites (Fig. 9.18) totaling 7.7 kg have been collected during routine guarrying operations (Schmitz etal., 1997,2001,2003). The 3.2-m-thick limestone layer in which they are found was deposited over -1.75 Myr in the mid-Ordovician. Despite being almost completely replaced by calcite, barite, and phyllosilicates, the meteorites are easily identified by their chondritic texture. Their identification as meteorites is confirmed by measurements of platinum-group elements. The chemical characteristics of relict spinels indicate that they are either L or LL chondrites. 

The following pages give a review of the chemistry of natural minerals, their typical occurrence in nature and their common mineral associations. This review is used to establish the major groupings of the common clay mineral species as a function of the chemical systems to which they can be related. Because various forms of silica as well as zeolites and organic materials are commonly associated with clays, these materials have been considered in the same manner as the phyllosilicates. It is evident that they have an influence on the clay mineralogy and that they form an integral part of clays in the broad sense of the term. However, they are not normally considered to be clay minerals. 

The number and exact composition of the sheets is used to classify the phyllosilicates. The most important classification for our purposes is the distinction between 1 1 and 2 1-type minerals (Figure 2.1). In 1 1 minerals such as kaolinite, the basal oxygens of the tetrahedral sheet are free to interact with octahedral OH groups forming hydrogen bonds. In contrast, 2 1 minerals such as pyrophyllite or talc contain two tetrahedral sheets sandwiched around an octahedral sheet. These minerals have only basal oxygens exposed on the faces of the tetrahedral sheets and are linked by weak van der Waals forces. The weaker interaction of one 2 1 layer with a second 2 1 layer results in interlayer spaces which, depending on the particular mineral, may be available for contaminant intercalation. 

CLAYS. The terms chy or cloys commonly refer to cither rocks that are consolidated or unconsolidated sediments, nr a group of minerals having unique properties. Traditionally, clays (rocks) are distinctive in al least two properties that render them technologically useful plasticity and composition. Clays are predominantly composed of hydrous phyllosilicates. referred to as clay minerals. These are hydrous silicates of Al. Mg. K, anti He. and other less ahundanl elements. Clay minerals arc extremely fine crystals or particles, often colloidal in size and usually plate-like in shape. The nonclay mineral portion of clays (rocks) may consist of other minerals, portions of rocks, and organic compounds. 

Usually, there is fast exchange of the looked-at cations between several sites, typically the bulk solvent (water, most often) and the anionic head-group of the surfactant, or of a charged solid surface (for a 2 1 phyllosilicate) If the quadrupo-... 

Clay minerals are hydrous aluminum phyllosilicates made of sheets or layers composed of tetrahedra and octahedra. This mineral type includes the following groups kaolinite, smectite, illite, and chlorite. In the case of smectite, each layer comprises two sublayers of tetrahedra with an inserted octahedral layer, where, between layers, an interlayer space where the exchangeable cations are located is formed [131-133], In Figure 2.24... 

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