5- Phthalimido-2-methyl

Weitere Beispiele fur diese Art der Mitsunobu-Reaktion sind die Umwandlung eines 2,2-Diaryl-ethanols in 2-Amino-I-(4-benzyloxy-phenyl)-l-(2-benzyloxy-3-methoxy-phenyl)-ethan2 und die Umwandlung von 5-Hydroxy-2-methyl-l-hexen-3-in in 5-Phthalimido-2-methyl-l-hexen-3-in, das (wie oben formuliert) in 5-Amino-4-ethyl-l-hydroxy-2-methyl-2,3-hexadien ubergefuhrt werden kann3 ... 

Phthalimido-methyl)-l-[4- ( 2-pyridyl-sulfonyl)-phenylazo]-benzimidazol ... 

CH,),- 3-(Nitro-phthalimido-methyl)-I-oxo- cyclopentan 47-68 96-103 (Hexan/Ether)... 

Butan 2-Diazo-1,3-dioxo-l -(4-methoxy-phenyl)- X/l. 506 Essigsaure Phthalimido- -methyl-amid E7a. 683 (Cl - Phthalimido)... 

Chlonnethyl-4-methyl- 231 4-Chlormethyl-2-methyl- 30, 162 4-Chlormethyl-2-(5-nitro-2-furyl)- 36 4-Chlormethyl-5-nitro-2-phenyl- 243 2-Chlor-4-(4-methyl-phenyl)- 154 4-Chlormethyl-2-(phthalimido-methyl)- 32 4-Chlormethyl-2-(2-tetrahydropyranyl)- 33 4-Chlor-5-nitro-2-phenoxy- 291 2-Ch I or-4-(2-oxo-2H-1 -benzopyran- 3-y 1)- 2 7 5 2-(4-Ch or-phenyl)- 25, 306 2-Chlor-4-phenyl- 278, 292... 

Phthalimido-methyl-quinacridone (PMQ) derivatives have also been determined by FT-IR down to 5 % concentration in PV 19 and in PR 122 based on the absorbance of the carbonyl group near 1710 cm . Quinacridone sulfonic acid (QSA) has been measured at 18-75 % concentration in PV 19. 

Normal phase Thin Layer Chromatography (TLC) has been used for the detection of sulfonated pigment derivatives of copper phthalocyanine, quinacridones, perylenes, copper phthalocyanine sulfonamides, and phthalimido-methyl derivatives of quinacridones and copper phthalocyanines. 

SO Boiling Acetyl Benzoyl p-Toluene- sulphonyl Formyl 2,4-Dinitro- phenyl Phthalimido- methyl Miscellaneous... 

The 1-azirines obtained from the vapor phase pyrolysis of 4,5-disubstituted 1-phthalimido-1,2,3-triazoles (157) have been found to undergo further thermal reactions (71CC1S18). Those azirines which contain a methyl group in the 2-position of the ring are cleaved to nitriles and phthalimidocarbenes, whereas those azirines which possess a phenyl substituent in the 2-position rearrange to indoles. 

Section 5.10.3.2). Treatment of methyl 6-phthalimido penicillinate (jR)-sulfoxide (40) with JV-chlorosuccinimide in refluxing carbon tetrachloride gives an epimeric mixture of sulfinyl chlorides (41) which are ring closed to epimeric 3-methylenecepham sulfoxides (42a) using tin(IV) chloride. Reduction with phosphorus tribromide gives the desired methyl 7-phthalimido-3-methylenecepham 4-carboxylate (42b). 

H-Azepine, 2-methyl-1-methoxycarbonyl-rearrangement, 7, 504 1 //-Azepine, 3-methyl-1 -methoxycarbonyl-cycloaddition reactions, 7, 520 IH-Azepine, 1-phenyl-synthesis, 7, 542 1 H-Azepine, N-phthalimido-formation, 7, 508 IH-Azepine, N-sulfonyl-UV spectra, 7, 501 1 H-Azepine, tetrahydromethylene-synthesis, 7, 540 IH-Azepine, N-p-tosyl-protonation, 7, 509 synthesis, 7, 537 3H-Azepine, 3-acyl-2-alkoxy-synthesis, 7, 542-543 3H-Azepine, 3-acyl-2-methoxy-rearrangements, 7, 505 3H-Azepine, 2-alkoxy-hydrolysis, 7, 510... 

H-Azepine, 2-(o-hydroxyphenyl)-synthesis, 7, 538 3 H-Azepine, methyl- H NMR, 7, 495 3H-Azepine, 3-methylring inversion barrier, 7, 14 3 H-Azepine, 2-methylene-isomerization, 7, 505 3H-Azepine, 7-(N-phthalimido) synthesis, 7, 538 4H-Azepine, 4,5-dihydro-cyclization, 7, 524... 

Aziridine, 2,3-diphenyl-l-(2,4,6-trinitrophenyl)-irradiation, 7, 61 Aziridine, 1,2-divinyl-rearrangement, 7, 539 Aziridine, 2,3-divinyl-rearrangement, 7, 42, 65, 539 Aziridine, N-ethyl-inversion, 7, 6 Aziridine, 2-halo-reactions, 7, 74 Aziridine, A/-halo-invertomers, 7, 6 Aziridine, 2-methyl- N NMR, 7, 11 Aziridine, methylene-ring-ring valence isomerizations, 7, 22 synthesis, 7, 92 Aziridine, iV-nitroso-reactions, 7, 74 Aziridine, iV-phosphino-inversion, 7, 7 Aziridine, 1-phthalimido-UV irradiation, 7, 62-63 Aziridine, l-(3-thienyl)-2-vinyl-rearrangement, 4, 746 Aziridine, 7V-trimethylsilyl-inversion, 7, 7 Aziridine, 1,2,3-triphenyl-irradiation, 7, 61 Aziridine, vinyl-isomerization, S, 287 Aziridinecarboxylic acid ring expansion, 7, 262 Aziridine-2,2-dicarboxylic acid, 1-methoxy-diethyl ester... 

Isocyanide, benzyl, 55, 98 Isocyanide, butyl-, 55, 98 Isocyanide, cyclohexyl-, 55, 98 ISOCYANIDE, 1,1-dimethylethyl- [Isocy-amde, tert-butyl-], 55,96 Isocyanide, dodecanyl- 55,98 Isocyanide, ethyl- 55,98 Isocyanide, methyl-, 55, 98 Isocyanide, phenyl-, 55, 98 1//Isoindole 1,3(2//) dione, 2 amino [Phthahmidc, N-amino-], 55, 115 1//-ISOINDOLE-1,3(2//)-DIONE, trans-( )-2-(2,3-diphenyl-l-aziridinvl)-[Azindine, frans-2,3-diphenyl-l-phthalimido-], 55, 115 ISOXAZOLE, 3-(4-chlorophenyl)-5-(4-methoxy phenyl)-, 55, 39 Isoxazole 5-(4-chlorophenyl)-3-(4-meth-oxyphenyl)-, 55, 42... 

Neuere Beispiele fur die Anwendung der Gabriel-Synthese in ihrer urspriinglichen Form sind u.a. die Herstellung von 4-Chlor-l-phthalimido-2-buten aus l,4-Dichlor-2-buten (65%)1 sowie die erste Stufe der folgenden Synthese von zwei allenischen Amino-alko-holen, 5-Amino-4-ethyl-l-hydroxy-2-methyl-2,3-hexadien (I R =H, R2=R3 = CH3 ... 

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