Phthalimide, N 2-bromoethyl

Phthalic acid, 32, 67 Phthalic anhydride, 32, 19 PHTHALIMIDE, N-2-BROMOETHYL-, 32, 18 PlMELIC ACID, 7-0X0-, DIETHYL ESTER,... 

Fluorophenyl)-pyrid-2-yl acetonitrile N-(2-Bromoethyl)phthalimide 3-(Imidazol-4-yl)-propylamine N-Benzoyldiphenylimidocarbonate... 

The synthesis of DAAmEP was conducted in three steps. The first step was a Michaelis-Arhuzov reaction between N-(2-bromoethyl)phthalimide and an excess of triethyl phosphite under reflux at 160 °C for 12 h. In the second step, the reaction between the resulting phthalimide and hydrazine led to the formation of (2-aminoethyl)phosphonic acid diethyl ester. The final step consisted of the reaction between the actyloyl chloride and the diethyl ester, which was achieved in the presence of poly(4-vinylpyridine), 2% crosslinked, to trap the hydrochloric acid produced during the acryloylation. The final DAAmEP monomer was obtained after purification by chromatography on silica gel. All intermediate products were characterized by H and P NMR. The H NMR spectrum of the DAAmEP monomer allowed validation of the expected chemical structure and as a consequence the synthetic pathway. RAFT homopolymerization of DAAmEP was carried out with two different trithiocarbonate chain transfer agents (see Scheme 2.6). 

Phosphonic acid, (phthalimidomethyl)-, diethyl ester, 65, 119 Phosphorazidic acid, diphenyl ester (26386-88-9), 68,1 Phosphoric triamide, hexamethyl- (680-31-9), 66, 51, 94 Phosphorodichloridic acid, 2-chloroethyl ester, 65, 68 Phosphorous acid, triethyl ester, 65, 108.119 Phosphorus oxychloride, 66,173, 176 67,1 68, 41,162 Phosphorus tribromide (7789-60-8), 67, 210 Phthalimide, N-(bromoethyl)-, 65, 119 Phthalimide, N-(hydroxymethyl)-, 65,119 Pig liver esterase, 69, 20... 

Polyamine chain extension, 48-56 by acrylamide 51, 52. 53 by aziridine 48,49 by l-bromo-3-chloropropane, 55 by (2-bromoethyl)phthalimide, 51 by 3-bromopropylphthalimide, 53 by chloroacetonitrilc, 51 by chloroacetyl chloride. 50 by lV-(2-chloroethyl)acetamide, 52 by derivatives of chloroacetic acid. 50 by dichloro(o)-bromoalkyl)boranes. 56 by IV-ethylchloroacetamide, 52 by 3-phthalimidopropyl tosylate, 54 by /V-tosyl-2-bromoethylamine, 49 by 2-(N-tosylamino)ethyl tosylate. 49 by Af-tosylaminoacetyl chloride, 50 Polyamino diols. 59 Polyaza-crown macrocycles. 349-367 alkyl-substituted. 364.365 from bis-sulfonamides, 358-361 from diacid dichlorides, 352-357 from diesters, 352-357 from dihalides, 362-366 from diols, 366 from ditosylates. 362-366 Polyaza-crown macrocycles (miscellaneous), table. 392... 

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