Photographic sensitivity

Selenazoles and their derivatives, that is. selenazolines and selenazo-lidines. aremainh used in cyanine-type dyes and photographic sensitizers as well as in pharmacology and chemotheraphs. 

In certain carbocyanines. used as photographic sensitizers in silver halide emulsions, selenazoline rings linked bv trimethine bridges are found (56, 72). 

Photographic gelatin Photographic materials Photographic plates Photographic sensitizers... 

Spectral Sensitization. The intrinsic absorption, and therefore the intrinsic photographic sensitivity, of silver bromide and silver iodobromide microcrystals falls off rapidly for wavelengths greater than 500 nm (see Fig. 2). In fact, silver chloride crystals have almost no sensitivity in the visible... 

More recent research provides reversible oxidation-reduction potential data (17). These allow the derivation of better stmcture-activity relationships in both photographic sensitization and other systems where electron-transfer sensitizers are important (see Dyes, sensitizing). Data for an extensive series of cyanine dyes are pubflshed, as obtained by second harmonic a-c voltammetry (17). A recent "quantitative stmcture-activity relationship" (QSAR) (34) shows that Brooker deviations for the heterocycHc nuclei (discussed above) can provide estimates of the oxidation potentials within 0.05 V. An oxidation potential plus a dye s absorption energy provide reduction potential estimates. Different regression equations were used for dyes with one-, three-, five-methine carbons in the chromophore. Also noted in Ref. 34 are previous correlations relating Brooker deviations for many heterocycHc nuclei to the piC (for protonation/decolorization) for carbocyanine dyes the piC is thus inversely related to oxidation potential values. 

Oxadiazoles, amino-alkylation, 6, 431 as photographic sensitizer, 6, 446 ring cleavage, 6, 434 tautomerism, 6, 381... 

There is also a large number of synthetic heterocyclic compounds with other important practical applications, as dyestuffs, copolymers, solvents, photographic sensitizers and developers, as antioxidants and vulcanization accelerators in the rubber industry, and many are valuable intermediates in synthesis. 

The pharmacological activities of other derivatives of these ring systems are examined intensively. Whereas other representatives of the above ring systems are patented as photographic sensitizers, catalysts for curing polyisocyanates, or dyes for acrylic nylon, polyester filters, and photographic material. 

Modern life and civilization opened the way to other important practical applications of heterocycles, for example dyestuffs, copolymers, solvents, photographic sensitizers and developers, and in the rubber industry antioxidants and vulcanization accelerators. Some of the sturdiest polymers, such as Kevlar, have aromatic rings. Melamines (2,4,6-triamino-substituted s-triazines) are monomers with numerous applications as both homopolymers and copolymers. Scheme 9 shows a few examples of compounds with various applications in our daily life, having in common the same building block, the aromatic s-triazine. 

Berg, W. F. Photographic sensitivity and chemical sensitization of emulsions. 

Carroll, B. H., and W. West Optical sensitization of photographic emulsions. Fundamental mechanisms of photographic sensitivity, p. 162. London Butter-worth s Sci. Publ. 1951-... 

On the role of crystal imperfections in photographic sensitivity. Z. Physik 138, 381 (1954). 

Replacement of the latent image silver by gold in the exposed photographic sensitive layer increases the developability (James et at., 31). Since the mass of developed silver depends only upon the number of developed nuclei, the gold treatment has obviously increased the number of active nuclei. Hence, smaller gold nuclei (in terms of numbers of atoms) than silver can initiate development, unless the treatment used to effect a replacement of silver by gold has resulted in something more than a simple replacement. 

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