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Photochemistry salts

Photochemistry, photophysical properties and photosensitization of 7 were investigated (99MI37, 99MI42, 99MI64, 01MI23). Preparation and usage of nitrate salt of 7 were patented (01MIP14). [Pg.295]

There is a multiplicity of pathways for thermal dediazoniations. An analogous situation is to be expected for photochemical dediazoniations. Based on the general experience that light-sensitive reactions often involve free radical intermediates, it was commonly assumed that all photolytic dediazoniations are free radical reactions. Horner and Stohr s results (1952), mentioned above, could lead to such a conclusion. More sophisticated methods of photochemistry also began to be applied to investigations on arenediazonium salts, e. g., the study of photolyses by irradiation at an absorption maximum of the diazonium ion using broad-band or monochromatic radiation. This technique was advocated by Sukigahara and Kikuchi (1967 a, 1967 b,... [Pg.277]

Photo-de-diazoniation has found relatively little application in organic synthesis, as is clearly evident from the annual Specialist Periodical Reports on Photochemistry published by the Royal Society of Chemistry. Since the beginning of these reports (1970) they have contained a section on the elimination of nitrogen from diazo compounds, written since 1973 by Reid (1990). In the 1980s (including 1990), at least 90% of each report is concerned with dediazoniations of diazoalkanes and non-quinon-oid diazo ketones, the rest being mainly related to quinone diazides and only occasionally to arenediazonium salts. [Pg.281]

Partitioning of carbocations between addition of nucleophiles and deprotonation, 35, 67 Perchloro-organic chemistry structure, spectroscopy and reaction pathways, 25, 267 Permutations isomerization of pentavalent phosphorus compounds, 9, 25 Phase-transfer catalysis by quaternary ammonium salts, 15, 267 Phenylnitrenes, Kinetics and spectroscopy of substituted, 36, 255 Phosphate esters, mechanism and catalysis of nucleophilic substitution in, 25, 99 Phosphorus compounds, pentavalent, turnstile rearrangement and pseudoration in permutational isomerization, 9, 25 Photochemistry, of aryl halides and related compounds, 20, 191 Photochemistry, of carbonium ions, 9, 129... [Pg.359]

Recently, nonionic acid precursors based on nitrobenzyl ester photochemistry have been developed for chemically amplified resist processes (78-80). These ester based materials (Figure 8) exhibit a number of advantages over the onium salt systems. Specifically, the esters are easily synthesized, are soluble in a variety organic solvents, are nonionic in character, and contain no potential device contaminants such as arsenic or antimony. In addition, their absorption characteristics are well suited for deep-UV exposure. [Pg.13]

Merocyanine Dye Method for Acid Analysis. Resist photochemistry can often be monitored by the changes in ultraviolet absorption spectra associated with a bleaching of the sensitizer absorbance. In the case of resist systems with triphenylsulfonium salts, no change in the film absorption is observed on irradiation. In order to determine the amount of acid produced, a direct method for acid analysis was required. A highly sensitive method was desirable since the amount of acid produced is approximately 10 6 mmol for a 1 micrometer thick film on a 2 inch wafer. Furthermore a nonaqueous technique is preferred in order to avoid hydrolysis of the hexafiuoroantimonate salt. Hydrolysis gives hydrogen fluoride (14) which makes accurate acid determination more difficult. [Pg.30]

The irradiation of films prepared from 1% triphenylsulfonium salts in poly(4-t-butoxycarbonyloxystyrene) with lithographically useful doses of 254 nm light generates acid which is less than 0.1% of the t-BOC groups. The efficiency of the photochemistry is several times less than the efficiency of acid generation from triphenylsulfonium salts in solution. The catalytic chain is about 1000 for the t-BOC deprotection step at 100°C. This implies that catalyst diffusion during postbake is on the order of 50A... [Pg.37]

The charge-transfer salts of carbonylmetallates are thus distinguished from the iodide salts in the breadth of photochemistry that obtains upon exposure to visible light. For example, the continuous irradiation of the... [Pg.214]

The solid state photochemistry of the salts of carboxylic acids with optically active primary amines has been studied111. Enantiomeric excesses ranging from 14-80% can be achieved (equation 59). [Pg.710]

Electron-poor olefins with higher oxidation potentials may decrease the rate of electron transfer and other processes competing for deactivation of the iminium salt excited states may increase. Alternate reaction pathways involving olefin-arene 2 + 2 cycloaddition may take place in the photochemistry of 133 with electron-poor olefins (equation 62)120,121. [Pg.711]

The allylsilane-iminium salt photochemistry has been found useful for the development of novel spirocyclization methodologies (equation 69)124,125. [Pg.714]

During the last ten years, studies of luminescence and photochemistry of polypyridyl Ru(II), Rh(III) and Co(III) complexes, porphyrins and uranyl salts, in the presence of biological macromolecules such as DNA, have been the focus of increasing research work. The interest in such coordination compounds stems from their easily tunable properties. Not only their size and shape but also their... [Pg.27]

Single crystal-to-single crystal reactions are quite rare in solid-state organic photochemistry, and we were fortunate to discover a second example in the Yang photocyclization of the 1-phenylethylamine salt of 2-methyl-2-benzoyl-p-carboxylic acid 39 [37]. [Pg.19]

The X-ray analyses reveal that, as in the case of salt 37b, enantio- and dia-stereoselectivity in the solid-state photochemistry of salt 39 are conformationally... [Pg.19]

From the foregoing discussion, it is clear that DPM rearrangements are very general for a variety of 1,4-unsaturated systems, such as, 1,4-dienes, (3,7-unsaturated aldehydes and ketones, and different 1-aza-1,4-diene derivatives. Surprisingly, the literature was devoid of studies describing the photoreactivity of the closely related 2-aza-1,4-diene derivatives. For many years, the only studies in this area were carried out by Mariano and his co-workers [60] on the photochemistry of iminium salts derived from 2-aza-1,4-dienes. The results obtained demonstrated the synthetic utility of the photocyclizations of iminium salts to different heterocycles, in reactions that are initiated by intramolecular single electron transfer [60]. [Pg.20]

Onium Salts, Photochemistry and Photophysics of (DeVoe, Olofson, and... [Pg.179]


See other pages where Photochemistry salts is mentioned: [Pg.388]    [Pg.774]    [Pg.277]    [Pg.4]    [Pg.263]    [Pg.315]    [Pg.13]    [Pg.141]    [Pg.724]    [Pg.210]    [Pg.221]    [Pg.146]    [Pg.212]    [Pg.215]    [Pg.217]    [Pg.236]    [Pg.683]    [Pg.710]    [Pg.710]    [Pg.25]    [Pg.27]    [Pg.28]    [Pg.257]    [Pg.259]    [Pg.260]   
See also in sourсe #XX -- [ Pg.33 ]




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