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Phenoxy butyraldehyde

Lallemand et al. have found a pericyclic-anionic domino three-component reaction to prepare highly functionalized alcohols.115931 This reaction was originally developed by Vaultier, Hoffmann et al.[59bl Diels-Alder reaction of a 1,3-dienylboronate with an acrylate yields a mixture of endo and exo diastereomers of the coupled allylboronate, which in the presence of an aldehyde such as 4-phenoxy-butyraldehyde undergoes an allylation reaction. After hydrolysis the resulting diastereomeric alcohols are obtained in about 50 % yield, whereby two new stereogenic centers are formed in a stereoselective fashion. [Pg.53]

On the other hand allyl phenyl ether was found to give only phenoxy-butyraldehyde with a selectivity up to 84% [971]. [Pg.55]


See also in sourсe #XX -- [ Pg.55 ]




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4- phenoxy

Butyraldehyde

Butyraldehydes

Phenoxys

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