Phenols halogeno

Almost insoluble in cold water. Higher alcohols (including benzyl alcohol), higher phenols (e.g., naphthols), metaformaldehyde, paraldehyde, aromatic aldehydes, higher ketones (including acetophenone), aromatic acids, most esters, ethers, oxamide and domatic amides, sulphonamides, aromatic imides, aromatic nitriles, aromatic acid anhydrides, aromatic acid chlorides, sulphonyl chlorides, starch, aromatic amines, anilides, tyrosine, cystine, nitrocompounds, uric acid, halogeno-hydrocarbons, hydrocarbons. 

Photoaddhion of electron donor olefins such as vinyl ethers and stilbene to variously methyl and halogeno-substituted 1,4-benzoquinones resulted in the formation of dihydrobenzofurans via a dienone-phenol rearrangement of the primary product spirooxetanes <96H(43)619>. High-temperature water seems to be an alternative to use of acid catalysts or organic solvents by the cyclization of allyl phenyl ethers to dihydrobenzofurans <96JOC7355>. 

Benzofurans have also been prepared by the coupling of o-halogeno-phenols with cuprous aryl acetylides and ensuing cyclization of intermediate diarylacetylides134-136 (Scheme 74). 

Formation of phenols by replacement of boron, oxoalkyl, carboxy,formyl, nitro, triazeno, sulphonamido, halogeno and thailic group... 

Phenols react with a-halogeno- -ketoesters to give aryloxy compounds. Cyclization with concentrated sulfuric acid yields 2-alkoxycarbonylbenzofurans (Scheme 56) <63OSC(4)590>. 

Sulfonic acid Isomer distribution data for the SO3 sulfonation are available for alkylbenzenes and their halogeno derivatives phenol and anisole, and their methyl, halogeno, and hydroxy and methoxy derivatives and naphthalene, and Its methyl, and hydroxy and methoxy derivatives. SO3 sulfonation Isomer distribution data are also available for a number of polycyclic aromatic hydrocarbons and 1,6-methano[10]annulenes, including some alkyl derivatives. ... 

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