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Phase-transfer reactions, industrial applications

Arylation, olefins, 187, 190 Arylketimines, iridium hydrogenation, 83 Arylpropanoic acid, Grignard coupling, 190 Aspartame, 8, 27 Asymmetric catalysis characteristics, 11 chiral metal complexes, 122 covalently bound intermediates, 323 electrochemistry, 342 hydrogen-bonded associates, 328 industrial applications, 8, 357 optically active compounds, 2 phase-transfer reactions, 333 photochemistry, 341 polymerization, 174, 332 purely organic compounds, 323 see also specific complexes Asymmetric induction, 71, 155 Attractive interaction, 196, 216 Autoinduction, 330 Axial chirality, 18 Aza-Diels-Alder reaction, 220 Azetidinone, 44, 80 Aziridination, olefins, 207... [Pg.192]

Ch. M. Starks, Ch. L. Liotta, M. Hal-pern, Phase Transfer Catalysis Fundamentals, Applications, and Industrial Perspectives, Chapman and Hall, New York, 1994. Specifically Chapter 13 Phase transfer catalysis - transition metal cocatalyzed reactions, p. 594. [Pg.285]

Interests in the phase transfer catalysis (PTC) have grown steadily for the past several years [68-70]. The use of PTC has recently received industrial importance in cases where the alternative use of polar aprotic solvents would be prohibitively expensive [71-74]. Thus, the potential application of the phase transfer catalyzed aromatic nucleophilic displacement reactions between phenoxide or thiophenoxide and activated systems has... [Pg.42]

Rate enhancements for these types of reaction have been reported to be as high as 200-fold, and the selectivity of the reaction was found to be very substrate dependent. These reactions must be conducted in dipolar aprotic solvents in the absence of water. Although tetramethylammonium chloride is too polar to find widespread application as a phase transfer agent, it has good thermal stability, and this, combined with its low cost, has resulted in its large scale industrial use in phase transfer catalysed aromatic nucleophilic fluorinations. [Pg.121]

Water is a unique solvent because of its high polarity and ability to form a network of H-bonds. It is immiscible with many organic solvents and is therefore a suitable solvent for use in biphasic reactions in which catalysts are made preferentially soluble in the aqueous phase. Phase transfer catalysis allows the use of aqueous reagents with substrates that have low solubility in water. That water is abundant and totally non-toxic make it the perfect clean solvent, provided that solubility issues can be overcome, and it is in use as a solvent on an industrial scale for polymerization, hydroformylation, and a range of organic chemistry involving PTC. These applications are discussed further in Chapters 7-11. [Pg.126]

Of primary interest for the industrial application of monolith reactors is to compare them with other conventional three-phase reactors. Two main categories of three-phase reactors are slurry reactors, in which the solid catalyst is suspended, and packed-bed reactors, where the solid catalyst is fixed. Generally, the overall rate of reactions is often limited by mass transfer steps. Hence, these steps are usually considered in the choice of reactor type. Furthermore, the heat transfer characteristics of chemical reactors are of essential importance, not only due to energy costs but also due to the control mode of the reactor. In addition, the ease of handling and maintenance of the reactor have a major role in the choice of the reactor type. More extensive treatment of conventional reactors can be found in the works by Gianetto and Silveston [11], Ramachandran and Chaudhari [12], Shah [13,14], Shah and Sharma [15], and Trambouze et al. [16], among others. [Pg.245]

Phase-transfer catalysis (PTC) is the most widely used method for solving the problem of the mutual insolubility of nonpolar and ionic compounds. Basic principles, synthetic uses, industrial applications of PTC, and its advantages over conventional methods are well documented [1-3]. PTC has become a powerful and widely accepted tool for organic chemists due to its efficiency, simplicity, and cost effectiveness. The main merit of the method is its universality. It may be applied to many types of reactions involving diverse classes of compounds. An important feature of PTC is its computability with other methods for the intensification of biphasic reactions (sonolysis, photolysis, microwaving, etc.) as well as with other types of catalysis, in particular, with transition-metal-complex catalysis. Homogeneous metal-complex catalysis under PTC conditions involves the simul-... [Pg.953]

Easy and efficient access routes to heterocyclic complexes are of significant interest in organic chemistry and its application in synthesis in both laboratory and industry. During recent years, several novel routes towards such compounds in aqueous media have been described. 2-Substituted 3,4-dihydro-2H-l,4-benzoxa-zines have been prepared in excellent yields and short reaction times through the cyclization of hydroxysulfonamides in water under phase-transfer catalysis conditions (Scheme 3) [26],... [Pg.633]

Mass transfer, an important phenomenon in science and engineering, refers to the motion of molecules driven by some form of potential. In a majority of industrial applications, an activity or concentration gradient serves to drive the mass transfer between two phases across an interface. This is of particular importance in most separation processes and phase transfer catalyzed reactions. The flux equations are analogous to Ohm s law and the ratio of the chemical potential to the flux represents a resistance. Based on the stagnant-film model. Whitman and Lewis [25,26] first proposed the two-film theory, which stated that the overall resistance was the sum of the two individual resistances on the two sides. It was assumed in this theory that there was no resistance to transport at the actual interface, i.e., within the distance corresponding to molecular mean free paths in the two phases on either side of the interface. This argument was equivalent to assuming that two phases were in equilibrium at the actual points of contact at the interface. Two individual mass transfer coefficients (Ld and L(-n) and an overall mass transfer coefficient (k. ) could be defined by the steady-state flux equations ... [Pg.239]


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See also in sourсe #XX -- [ Pg.641 , Pg.642 , Pg.643 , Pg.644 , Pg.645 ]




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Application phase

Phase industrial applications

Phase-transfer reactions

Reaction application

Transfer applications

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