Peroxy propionic acid

Benzeneperoxyseleninic acid, 2337 Benzeneperoxy sulfonic acid, 2341 3-Chloroperoxybenzoic acid, 2676 Diperoxyazelaic acid, 3189 Diperoxyterephthalic acid, 2925 Monoperoxysuccinic acid, 1542 Peroxyacetic acid, 0837 Peroxybenzoic acid, 2733 3-Peroxycamphoric acid, 3348 Peroxycrotonic acid, 1535 Peroxyformic acid, 0420 Peroxyfuroic acid, 1837 Peroxyhexanoic acid, 2514 Peroxy propionic acid, 1236 Peroxytrifluoroacetic acid, 0666 Trichloroperoxyacetic acid, 0659 See 1 /-DI(BENZOYLPEROX Y)ARYLIODINES POLYMERIC PEROXYACIDS ORGANIC PEROXIDES... 

Peroxy propionic acid (C2H5CO3H) [340], peroxylauric acid (C11H23CO3H) [174], and other aliphatic peroxy acids [341] are used rarely, and the results do not differ appreciably from those obtained from more common peracids. The same is true of peroxypentafluorobenzoic acid, C FjCOjH, which is obtained from pentafluorobenzaldehyde and ozone and is used for epoxidations the Baeyer-Villiger reaction and the preparation of amine oxides, sulfoxides, and sulfones [342]. 

Propaneperoxoic acid, see Peroxy propionic acid, 1236 f 2-Propanethiol, 1290 t Propanethiol, 1289... 

In addition to decarboxylation, the oxidation of acids yields hydro-peroxy, hydroxy, keto groups, lactones, and mono- and dicarboxylic acids of lower molecular weight. The mechanism of the oxidation of acids is similar to that for hydrocarbons. The reactivity of mono- [300] and dicarboxylic acids [216] with respect to cumylperoxy radicals was measured by oxidation in the presence of cumyl hydroperoxide as source of R02 (see Table 15). The reactivities of methylenic groups in mono- and dicarboxylic acids and in rc-paraffin acids are close. For example, at 100° C, feCH2 X 102 (1 mole-1 s-1) = 4.8 (n-decane), 10.0 (glutaric, sebacic, j3,7 groups), 6.4 (a-CH2 of dibasic acids), 8.0 (for monocarboxylic acids), and 11.0 (>CH2 for propionic acid). 

Thus, it is possible to assume that properties esters 2-(N-acetylamid)-3-(3 5 -di-tert.butyl-4 -hydroxyphenyl)-propionic acid are bound to geometry of communications between kernels of atoms in a molecule and possibility of electron transition with an antioxidant on the lowest vacant orbital of molekule peroxy radical. 

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