Peroxodisulfuryl difluoride

Apparently thermodynamically unstable, because when the peroxodisulfuryl difluoride-boron nitride reaction mixture was heated to 40°C, detonations occurred. [Pg.85]

See Chlorine dioxide Carbon monoxide Oxygen (Liquid) Liquefied gases Peroxodisulfuryl difluoride Carbon monoxide... [Pg.220]

The crude fluorosulfate, produced as by-product in preparation of peroxodisulfuryl difluoride, was distilled into a cooled steel cylinder and, on warming to ambient temperature, the cylinder exploded. It decomposes at 200° C, but not explosively [1], Preparative and handling procedures are detailed [2], Further warnings on the need to handle with care have been given [3,4],... [Pg.1527]

Bis(fluoroformyl) peroxide, 0625 Bis-3-(2-furyl)acryloyl peroxide, 3640 Bis(trichloroacetyl) peroxide, 1361 Bis(trifluoroacetyl) peroxide, 1367 Diacetyl peroxide, 1537 Dibenzenesulfonyl peroxide, 3499 Dibenzoyl peroxide, 3639 Di-3-camphoroyl peroxide, 3807 Dicrotonoyl peroxide, 2986 Dicyclohexylcarbonyl peroxide, 3667 Didodecanoyl peroxide, 3857 Di-2-furoyl peroxide, 3245 Dihexanoyl peroxide, 3554 Diisobutyryl peroxide, 3032 Diisopropyl peroxydicarbonate, 3034 Dimethanesulfonyl peroxide, 0931 Di-2-methylbutyryl peroxide, 3354 Di-l-naphthoyl peroxide, 3831 3,6-Dioxo-l,2-dioxane, 1445 Dipropionyl peroxide, 2442 Dipropyl peroxydicarbonate, 3035 Di-4-toluenesulfonyl peroxide, 3656 Peroxodisulfuryl difluoride, 4328 Phthaloyl peroxide, 2900 Potassium benzenesulfonylperoxosulfate, 2257 Potassium O-O-benzoylmonoperoxosulfate, 2684 (9-TriIIuoroacctyl-.S -lluorofonny 1 thioperoxide, 1050 See PEROXIDES, PEROXYCARBONATE ESTERS... [Pg.109]

Palladium(II) oxide, 4825 Palladium(IV) oxide, 4835 Perchloric acid, 3998 Periodic acid, 4425 Permanganic acid, 4434 Peroxodisulfuric acid, 4482 Peroxodisulfuryl difluoride, 4328 Peroxomonosulfuric acid, 4481 Peroxytrifluoroacetic acid, 0666 Platinum hexafluoride, 4371 Platinum(IV) oxide, 4836 Plutonium hexafluoride, 4372 Potassium bromate, 0255 Potassium chlorate, 4017 Potassium dichromate, 4248 Potassium iodate, 4619 Potassium nitrate, 4650 Potassium nitrite, 4649 Potassium perchlorate, 4018 Potassium periodate, 4620 Potassium permanganate, 4647 Rhenium hexafluoride, 4373 Rubidium fluoroxysulfate, 4309 Ruthenium(VIII) oxide, 4862 Selenium dioxide, 4838 Selenium dioxide, 4838 Silver permanganate, 0021 Sodium chlorate, 4039 Sodium chlorite, 4038 Sodium dichromate, 4250 Sodium iodate, 4624 Sodium nitrate, 4721 Sodium nitrite, 4720... [Pg.309]

A,A-Difluorohydroxylamine-0-sulfonyl fluoride is prepared by the photolysis of tetrafluorohydrazine and sulfur trioxide (55% yield)17 or essentially quantitatively by the reaction of N2 F4 and peroxodisulfuryl difluoride (S206 F2 J.18... [Pg.35]

The crude fluorosulfate, produced as by-product in preparation of peroxodisulfuryl difluoride, was distilled into a cooled steel cylinder and, on warming to ambient... [Pg.1588]

Bis(fluorosulfuryl)peroxide, see Peroxodisulfuryl difluoride, 4322 Bis-3-(2-furyl)acryloyl peroxide, 3633 Bis(hexafluorobenzene)chromium(0), 3415 Bis(hexafluorobenzene)cobalt(0), 3413 Bis(hexafluorobenzene)iron(0), 3418 Bis(hexafluorobenzene)nickel(0), 3419 Bis(hexafluorobenzene)titanium(0), 3420 Bis(hexafluorobenzene)vanadium(0), 3421... [Pg.2053]

Dipropionyl peroxide, 2436 Dipropyl peroxydicarbonate, 3030 Peroxodisulfuryl difluoride, 4322 Phthaloyl peroxide, 2895 Potassium benzenesulfonylperoxosulfate, 2250 Potassium O—O-benzoylmonoperoxosulfate, 2680 O-Trifluoroacetyl-S -fluoroformyl thioperoxide, 1047 See PEROXIDES, PEROXYCARBONATE ESTERS... [Pg.2296]

Palladium(II) oxide, 4819 Palladium(IV) oxide, 4829 Perchloric acid, 3992 Periodic acid, 4419 Permanganic acid, 4428 Peroxodisulfuric acid, 4476 Peroxodisulfuryl difluoride, 4322 Peroxomonosulfuric acid, 4475 Peroxytrifluoroacetic acid, 0662 Platinum hexafluoride, 4365 Platinum(IV) oxide, 4830 Plutonium hexafluoride, 4366 Potassium bromate, 0255 Potassium chlorate, 4011 Potassium dichromate, 4242 Potassium iodate, 4614 Potassium nitrate, 4645 Potassium nitrite, 4644 Potassium perchlorate, 4012 Potassium periodate, 4615 Potassium permanganate, 4642 Rhenium hexafluoride, 4367 Rubidium fluoroxysulfate, 4303 Ruthenium(VIII) oxide, 4856 Selenium dioxide, 4832 Selenium dioxide, 4832 Silver permanganate, 0021... [Pg.2502]

Gne of the most interesting simple inorganic compounds reported in recent years is peroxodisulfuryl difluoride, F—SO2—02—S02—F (mp, —55° C bp, 67° C). This is both a peroxo compound and an acid fluoride but prepared by the fiuorination of sulfur trioxide. The compound can be... [Pg.295]

Gillespie and Milne (2) have shown, by conductometric, spectro-photometric, and magnetic susceptibility measurements in fluorosulfuric acid, that the blue iodine species observed in strong acids is la. When iodine was oxidized by peroxodisulfuryl difluoride in fluorosulfuric acid, the concentration of the blue iodine species reached a maximum at the 2 1 Ij/SgOeFa mole ratio [Eq. (4)] and not at the 1 1 mole ratio as would... [Pg.52]

Lower chain alkanes that resist direct anodic oxidation in fluorosulfonic acid can be indirectly converted " . For that purpose peroxodisulfuryl difluoride is generated at the anode, being either platinum gauze or vitreous carbon, by constant current electrolysis in a divided cell charged with potassium fluorosulfonate in anhydrous fluorosulfonic acid then methane is introduced into the solution. Depending on the reaction conditions, at 45 °C selectively methyl fluorosulfonate (61% coulombic yield)... [Pg.784]

Tetrabutylammonium hydrogen sulfate s. under NaOCl Peroxodisulfuryl difluoride... [Pg.371]

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