Peroxides acyl, with hydrocarbons

Anderson, L. R. et al., J. Fluorine Chem., 1976, 7, 481-500 Five derivatives, including the 0-0 lithium or sodium salts of the hydrogen peroxide adduct of hexafluoroacetone (2-hydroxyhexafluoro-2-propyl hydroperoxide), and their reaction products with acyl halides, are less flammable or explosive than their hydrocarbon analogues, though less stable than the parent hydroperoxides. Relevant entries are ... 

The latter reaction (producing the labile acyl phosphate) is less favored at increasing chain-lengths, and attack occurs along the hydrocarbon chain, with formation of an organic peroxide. In the absence of oxygen, no acyl phosphate or peroxide is formed, but inorganic phosphate is liberated. 

DIEXHYLENE GLYCOL METHYL ETHER ACETATE (629-38-9) Combustible liquid (flash point 180°F/98°C). Moisture may cause decomposition with formation of acetic acid. Reacts violently with strong oxidizers, permanganates, peroxides, ammonium persulfate, bromine dioxide, calcium chlorate, chlorosulfonic acid, oleum, sulfuric acid, nitric acid, perchloric acid, and other strong acids. Incompatible with acyl halides, aliphatic amines, alkalis, boranes, isocyanates, nitrates. May form shock-sensitive mixtures with silver, cobalt, chlorinated hydrocarbons, nitromethane, chromium compounds. Attacks some plastics, rubber, and coatings. Attacks copper, brass, zinc. 

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