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Permanganate systems

Silker, W. B., Evaluation of the Ferrous-Permanganate System for Water... [Pg.147]

The amination of quinazoline (241) with sodium amide in DMA has been described to give 4-aminoquinazoIine (242) in 40% yield (60YZ245). In the potassium amide/liquid ammonia/potassium permanganate system of van der Plas, quinazoline gave 62% 242 and 2% 4,4 -diquinazolylamine (243) (Scheme 80) (82JHC1285). [Pg.66]

Xue, Y., He, Y, and Lu, J. Chemiluminescence reaction of imipramine-glyoxal-potassium permanganate system. Penxi Shiyanshi 18(3) 49-51, 1999. [Pg.266]

Liquid ammonia and potassium permanganate system were also effectively applied to introduce an imino group in the highly electron-deficient A-alkylazinium salts [30, 39]. [Pg.189]

In the case of acrylamide polymerization initiated by the citric acid/ permanganate system, the oxidation of citric acid leads to a keto-dicarbox-ylic acid, which, upon drastic oxidation, transformed into acetone and carbon dioxide [246]. The mechanism of the redox system is as follows ... [Pg.75]

Phenol can be oxidi2ed and hence removed, ie, to levels <20 / g/L, from wastewater (248). Moreover, addition of potassium permanganate to the return activated sludge results in reduction of odors issued from the aeration tanks of conventional activated sludge wastewater treatment plants without any change occurring to the microbiology of the system (249). [Pg.528]

Printed circuit boards manufacture is aided by the use of KMnO. Alkaline permanganate solution is used to remove resin smeared on the interior hole wall of multilayered printed circuit boards. Additionally the hole wall is etched, resulting in a surface with excellent adhesion characteristics, for electrodeless copper (250). The alkaline permanganate etchback system containing >60 g/L KMnO and 40-80 g/L NaOH at 70—80°C, is effective for difunctional, tetrafiinctional, and polyimide resin substrates, where the level of etchback is direcdy proportional to the immersion time (10—20 min) (251). [Pg.528]

Manufacture. The only current U.S. manufacturer of trimesic acid is Amoco Chemical Co. It is produced by oxidation of mesitylene (1,3,5-trimethylbenzene) via the Hquid-phase oxidation in acetic acid using the cobalt— manganese—bromine catalyst system (138). This is a variant of the system used to produce terephthaUc and isophthaUc acids as well as trimellitic anhydride. American Bio-Synthetics Corp. did produce it by batch oxidation of mesitylene with potassium permanganate. [Pg.498]

The crown ethers and cryptates are able to complex the alkaU metals very strongly (38). AppHcations of these agents depend on the appreciable solubihty of the chelates in a wide range of solvents and the increase in activity of the co-anion in nonaqueous systems. For example, potassium hydroxide or permanganate can be solubiHzed in benzene [71 -43-2] hy dicyclohexano-[18]-crown-6 [16069-36-6]. In nonpolar solvents the anions are neither extensively solvated nor strongly paired with the complexed cation, and they behave as naked or bare anions with enhanced activity. Small amounts of the macrocycHc compounds can serve as phase-transfer agents, and they may be more effective than tetrabutylammonium ion for the purpose. The cost of these macrocycHc agents limits industrial use. [Pg.393]

The reaction mixture is filtered. The soHds containing K MnO are leached, filtered, and the filtrate composition adjusted for electrolysis. The soHds are gangue. The Cams Chemical Co. electrolyzes a solution containing 120—150 g/L KOH and 50—60 g/L K MnO. The cells are bipolar (68). The anode side is monel and the cathode mild steel. The cathode consists of small protmsions from the bipolar unit. The base of the cathode is coated with a corrosion-resistant plastic such that the ratio of active cathode area to anode area is about 1 to 140. Cells operate at 1.2—1.4 kA. Anode and cathode current densities are about 85—100 A/m and 13—15 kA/m, respectively. The small cathode areas and large anode areas are used to minimize the reduction of permanganate at the cathode (69). Potassium permanganate is continuously crystallized from cell Hquors. The caustic mother Hquors are evaporated and returned to the cell feed preparation system. [Pg.78]

The cleavage of fused pyrazines represents an important method of synthesis of substituted pyrazines, particularly pyrazinecarboxylic acids. Pyrazine-2,3-dicarboxylic acid is usually prepared by the permanganate oxidation of either quinoxalines or phenazines. The pyrazine ring resembles the pyridine ring in its stability rather than the other diazines, pyridazine and pyrimidine. Fused systems such as pteridines may easily be converted under either acidic or basic conditions into pyrazine derivatives (Scheme 75). [Pg.190]

Tliis methodology has also been extended to the use of liquid methylamine/ potassium permanganate (LMA/PP system). When this system is applied to a number of 3-nitro-l,8-naphthyridines (92a-92g), the C-4 position could be successfully substituted by methylamino group yielding 93a-93f. Tire intermediary 4-methylamino-[Pg.305]

When submitted to oxidation by a 2 per cent, solution of permanganate, pinononic acid, CgHj Og, melting at 128° to 129° C., the semi-carbazone of which melts at 204° C. Lastly the constitution of verbenone, as expressed by the above formula, is further confirmed by the fact that the bicyclic system is convertible into a monocyclic system by boiling with 25 per cent, sulphuric acid, with the formation of acetone and 3-methylcyclohexene-(2)-one-(l). This cyclohexenone has been characterised by its semi-carbazone (melting-point 198° C.) and by its conversion into y-acetobutyric acid (melting-point 36° C). The oily liquid, which did not react with sulphite, was submitted to benzoylation after dilution with pyridine. It thus gave rise to a benzoate from which was... [Pg.228]


See other pages where Permanganate systems is mentioned: [Pg.112]    [Pg.555]    [Pg.572]    [Pg.112]    [Pg.284]    [Pg.463]    [Pg.45]    [Pg.43]    [Pg.128]    [Pg.496]    [Pg.112]    [Pg.43]    [Pg.72]    [Pg.73]    [Pg.112]    [Pg.555]    [Pg.572]    [Pg.112]    [Pg.284]    [Pg.463]    [Pg.45]    [Pg.43]    [Pg.128]    [Pg.496]    [Pg.112]    [Pg.43]    [Pg.72]    [Pg.73]    [Pg.12]    [Pg.287]    [Pg.380]    [Pg.515]    [Pg.521]    [Pg.528]    [Pg.161]    [Pg.226]    [Pg.280]    [Pg.157]    [Pg.54]    [Pg.134]    [Pg.360]    [Pg.410]    [Pg.302]    [Pg.304]    [Pg.432]    [Pg.486]    [Pg.538]   
See also in sourсe #XX -- [ Pg.77 ]




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Applications to the Ground State of Permanganate and Related Tetroxo Systems

Hydrogen peroxide-permanganate system

Potassium permanganate mixed solvent systems

Potassium permanganate system

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