Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Matrices Pauli

The gap between the energy and bottom eigenvalue is nonnegative. If the fe-matrix P moves to further decrease the energy, and if the Pauli matrix S moves to further increase the bottom eigenvalue, the gap narrows and possibly shrinks to zero. It is important to note that there are semidefinite programs where this gap cannot shrink to zero we discuss such an example later. However, In our special case where we vary fc-matrices and Pauli matrices, as we have defined them, the gap shrinks to zero. This is an important result for both theoretical and practical reasons a proof is supplied below. [Pg.73]

The subject of 0(3) electrodynamics was initiated through the inference of the Bl]> field [11] from the inverse Faraday effect (IFF), which is the magnetization of matter using circularly polarized radiation [11-20]. The phenomenon of radiatively induced fermion resonance (RFR) was first inferred [15] as the resonance equivalent of the IFE. In this section, these two interrelated effects are reviewed and developed using 0(3) electrodynamics. The IFE has been observed several times empirically [15], and the term responsible for RFR was first observed empirically as a magnetization by van der Ziel et al. [37] as being proportional to the conjugate product x A multiplied by the Pauli matrix... [Pg.125]

This result emerges self-consistently at all levels of physics, from the classical nonrelativistic to the quantum electrodynamic. On the nonrelativistic classical level, the technique of RFR is due to the interaction of B<3> with the Pauli matrix. One way of demonstrating this result, which has been observed empirically [37], is to extend the minimal prescription to complex A, starting... [Pg.130]

Similarly [42], the dot product of a complex circular Pauli matrix and a unit vector e(2> is... [Pg.114]

We next use the Pauli matrix representations of the spin angular momentum operator components in the instantaneous molecule-fixed axis system from equation (2.92) to rewrite the above relationships ... [Pg.56]

As mentioned in the Introduction, magnetic exchange is both electrostatic and quantum mechanical in nature. It is electrostatic because the relevant energies are related to the energy costs of overlapping electron densities. It is quantum mechanical because of the fundamental requirement that the total wavefimction of two electrons must be antisymmetric to the exchange of both the spin and spatial coordinates of the two electrons. The wavefimction is separable into a product of spatial wavefimction V (ri, r2) that is a function of the positions r and ri of the two electrons, and a spin coordinate wavefimction /(ai, ai), where ai is the Pauli matrix for the spin operator Si = lioi /2. Both lr r, ri) and x (fri, cri) can be symmetric or antisymmetric individually but the fundamental... [Pg.2474]

Problem 2.14 Identify the Pauli matrix above in the following form of the spin angular momentum along the z direction... [Pg.43]

Here 9 is the azimuthal angle in electronic space and is the corresponding Pauli matrix. As a consequence of (61, 62), the symmetry group of Hso is a continuous group with group parameter e and the symmetry operations... [Pg.90]

However, this limitation has a couple of exceptions, the lucky cases. One is the tetragonal E 0 big case discussed in Sect. 2.1 with the respective APES shown in Fig. 2b. As the JT Hamiltonian (1) is a diagonal matrix, the distortion coordinate Q can be shifted to the two minimum points at once. With the diagonal Pauli matrix in the exponent, the coordinate-shift operator has a simple diagonal form,... [Pg.715]

It includes Pauli matrix. Though nondiagonal, it can be transformed to a diagonal form with eigenvalues 1. Formally, it coincides with (1). The rest of the solution, including separation of the orbital exchange part (15), is the same as in Sect. 3 with no approximations involved. [Pg.716]

Then the Pauli matrix operators acting on these vectors yield the results... [Pg.9]

The operator a0 is identity. Because of the anticommutation relations, the Dirac operators cannot be multiplicative operators (numbers). They are not differential operators either because of the independence of px,Py,pz,Po,x,y,z,t. But what variable (degree of freedom) do the Dirac operators act upon In the chapter dealing with the electron spin we saw that there are the Pauli matrix operators (which obey the idempotency and anticommutation) acting on a two-component wave function (the two-component spinor)... [Pg.180]

Thus the Dirac operators are somehow related to the Pauli matrix operators. They can be represented by 4 x 4 matrices, viz. [Pg.180]

The same result can be obtained more easily for a field 5 in the z direction, since the corresponding Pauli matrix... [Pg.175]

The exponent containing the off-diagonal matrix elements is now expressed in terms of the 2x2 Pauli matrix... [Pg.571]


See other pages where Matrices Pauli is mentioned: [Pg.465]    [Pg.268]    [Pg.219]    [Pg.497]    [Pg.148]    [Pg.162]    [Pg.183]    [Pg.184]    [Pg.126]    [Pg.130]    [Pg.131]    [Pg.134]    [Pg.138]    [Pg.100]    [Pg.377]    [Pg.43]    [Pg.109]    [Pg.702]    [Pg.7]    [Pg.186]    [Pg.189]    [Pg.153]    [Pg.360]    [Pg.46]    [Pg.174]    [Pg.57]    [Pg.204]    [Pg.174]    [Pg.32]    [Pg.548]   
See also in sourсe #XX -- [ Pg.223 , Pg.237 ]

See also in sourсe #XX -- [ Pg.115 ]

See also in sourсe #XX -- [ Pg.113 , Pg.147 ]




SEARCH



Operator Pauli matrix

Pauli equation matrices

Pauli matrices corrections

Pauli spin matrices

Pauli, correlation matrix

Pauli, generally matrices

Pauly

© 2024 chempedia.info