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Ozone, reaction with alkenes

Mechanistic studies of ozone reactions with alkenes,... [Pg.294]

Ozone IS a powerful electrophile and undergoes a remarkable reaction with alkenes m... [Pg.262]

Ozonium Ion (H03+). Ozone is a resonance hybrid of canonical structures 50a-50d.135 Ozone does in fact act as a 1,3-dipole—that is, either as an electrophile or a nucleophile. The electrophilic nature of ozone has been recognized for a long time in its reactions with alkenes, alkynes, arenes, amines, phosphines,... [Pg.330]

Photolysis of atmospheric pollutants by solar radiation results in an increase of ozone concentration in certain urban areas and is the cause of a sequence of oxidation reactions with polymers. Ozone reacts with practically all organic materials especially with alkenes. The rate of its reaction with alkene is several orders of magnitude higher than that with alkane. The ratio of the rate constants of ozone with ethene/ethane is 1.5 x 105, with propene/propane 1.6 x 106, and with butene- 1/butane 1.1 x 106, at room temperature [5],... [Pg.193]

Ozone is an extremely reactive chemical. Its reaction with alkenes was discussed in Section 11.11. Although it is considered a pollutant in the lower atmosphere, its presence in the upper atmosphere has beneficial health effects due to its absorption of ultraviolet light. [Pg.616]

Ozone, while somewhat inconvenient to use, is way qiecific in its reactions with alkenes. It is widely employed for selective synthesis, for qualitative and quantitative analysis of unsaturated compounds, and for studying the position of double bonds in macromolecules. The nature of the products obtained from ozonolysis reactions is determitted by the way in which the reaction is carried out Different workup procedures (hydrolytic, reductive or oxidative) can be used to produce alcohols, aldehydes, ketones, carboxylic acids or esters. [Pg.542]

Explosive reaction with alkenes + diiodomethane, sulfur dioxide. Reacts violently with bromine, water, nitro compounds. Ignites on contact with air, ozone, methanol, or hydrazine. Reacts violently with nonmetal halides (e.g., arsenic trichloride or phosphorus trichloride) to produce pyrophoric triethyl arsine or triethyl phosphine. To fight fire, do not use water, foam, or halogenated extinguishing agents. Use dty materials, such as graphite, sand, etc. When heated to decomposition it emits toxic fumes of ZnO. See also ZINC COMPOUNDS. [Pg.499]

Ozone is a powerful electrophile and undergoes a remarkable reaction with alkenes in which both the cr and tt components of the carbon-carbon double bond are cleaved to give a product referred to as an ozonide. [Pg.240]

The simplest example of a dipole is probably ozone, which is well known for its reaction with alkenes. Its resonance hybrid is shown as 5.26. [Pg.113]

Alkylaziridines can be stereospecifically deaminated to alkenes by reaction with m-chioroperbenzoic acid (70AG(E)374). The reaction and work-up are carried out in the dark to avoid isomerization of the cw-alkene, and the mechanism is thought to involve an initial oxidation to an amine oxide followed by a concerted elimination. Aziridine oxides have been generated by treating aziridines with ozone at low temperatures (71JA4082). Two... [Pg.74]

The reaction of ozone with an aromatic compound is considerably slower than the reaction with an alkene. Complete ozonolysis of one mole of benzene with workup under non-oxidative conditions will yield three moles of glyoxal. The selective ozonolysis of particular bonds in appropriate aromatic compounds is used in organic synthesis, for example in the synthesis of a substituted biphenyl 8 from phenanthrene 7 ... [Pg.219]

Propose structures for alkenes that yield the following products on reaction with ozone followed by treatment with Zn ... [Pg.238]

Alkenes are reduced by addition of H2 in the presence of a catalyst such as platinum or palladium to yield alkanes, a process called catalytic hydrogenation. Alkenes are also oxidized by reaction with a peroxyacid to give epoxides, which can be converted into lTans-l,2-diols by acid-catalyzed epoxide hydrolysis. The corresponding cis-l,2-diols can be made directly from alkenes by hydroxylation with 0s04. Alkenes can also be cleaved to produce carbonyl compounds by reaction with ozone, followed by reduction with zinc metal. [Pg.246]

Compound A, C10H 8O, undergoes reaction with dilute H2S04 at 50 °C to yield a mixture of two alkenes, QpH ir>. The major alkene product, B, gives only cyclopentanone after ozone treatment followed by reduction with zinc in acetic acid. Identify A and B, and write the reactions. [Pg.253]

Alkynes, like alkenes, can be cleaved by reaction with powerful oxidizing agents such as ozone or KMnC, although the reaction is of little value and we mention it only for completeness. A triple bond is generally less reactive than a double bond and yields of cleavage products are sometimes low. The products obtained from cleavage of an internal alkyne are carboxylic acids from a terminal alkyne, CO2 is formed as one product. [Pg.270]

Ozone (332) generally combines with alkenes in a 1,3-dipolar fashion giving the so-called primary ozonides which recombine to 1,2,4-trioxolanes (ozonides). Its reaction with the parent MCP (1) is not known, whereas it reacts readily at... [Pg.57]

Grosjean, D., Grosjean, E., Williams, II, E.L. (1994) Atmospheric chemistry of olefins A product study of the ozone — alkene reaction with cyclohexane added to scavenge OH. Environ. Sci. Technol. 26, 186-196. [Pg.399]

Ozone vigorously reacts with the double bonds of alkenes and quite rapidly with the iT-bonds of aromatic rings. Its reaction with the C—H bonds of hydrocarbons occurs relatively slowly and is accompanied by the formation of free R and HCV radicals followed by the decomposition of the unstable radical H03 (see Chapter 3). [Pg.551]


See other pages where Ozone, reaction with alkenes is mentioned: [Pg.1310]    [Pg.78]    [Pg.441]    [Pg.73]    [Pg.439]    [Pg.252]    [Pg.595]    [Pg.611]    [Pg.82]    [Pg.921]    [Pg.1129]    [Pg.357]    [Pg.913]    [Pg.31]    [Pg.100]    [Pg.232]   
See also in sourсe #XX -- [ Pg.914 , Pg.1522 , Pg.1523 , Pg.1524 ]

See also in sourсe #XX -- [ Pg.267 , Pg.268 , Pg.269 , Pg.270 ]

See also in sourсe #XX -- [ Pg.188 ]




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