Ozone physiological reactions

One factor contributing to crop losses caused by ozone is the development of abnormal pigments which are viewed as discolored areas on foliage of ozone-sensitive cultivars. Such discoloration is esthetically unacceptable on leafy food crops and probably causes a reduction in the nutritional value of all foliar components used for food and feed. Biochemical and physiological reactions responsible for ozone-induced discolorations have not... 

Denitrification involves the sequential formation of nitrite, nitric oxide, and nitrous oxide. Two aspects of nitric oxide have attracted attention (a) chemical oxidation of biogenic nitric oxide to Nq, in the context of increased ozone formation (Stohl et al. 1996) and (b) the physiological role in mammalian systems (Feldman et al. 1993 Stuehr et al. 2004), in parasitic infections (James 1995), and in the inhibition of bacterial respiration (Nagata et al. 1998). Nitric oxide may be produced microbiologically in widely different reactions such as... 

In aqueous solution and without artificial ligands, aqua-Fe(I V) is formed in the reaction of Fe2+ with ozone [reaction (78)] (Logager et al. 1992 Jacobsen et al. 1997a,b), and under rather non-physiological conditions Fe(IV) and even higher oxidation states of iron have been generated and characterized by pulse radiolysis (Bielski 1991). 

Oxidation with ozone, under physiological conditions, follows the rate order uric acid ascorbic acid > glutathione. The amounts of ozone absorbed and antioxidant consumed have been simulated with a mathematical model and reaction rate constants of the oxidations have been evaluated.194 Various facets of transition metal-catalysed oxidation of benzylic compounds with ozone have been reported. The correlation of the effect of substituents with Hammett constants and steric factors has been discussed. The reaction seemed to proceed via a radical mechanism.195... 

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