Sulfur-oxygen bonds

Alkyl hydrogen sulfates can be converted to alcohols by heating them with water This IS called hydrolysis, because a bond is cleaved by reaction with water It is the oxygen-sulfur bond that is broken when an alkyl hydrogen sulfate undergoes hydrolysis... [Pg.246]

D. V-Nitrosamines Oxygen-Sulfur Bond Oxygen-Nitrogen Bond Oxygen-Phosphorus Bond Sulfur-Nitrogen Bond Sulfur-Halogen Bond Sulfur-Phosphorus Bond References... [Pg.969]

Consider now some cyclic sulfuranes with oxygen-sulfur bonds similar to the several thiaoxaspiraranes discussed previously (5, 6). The... [Pg.49]

The broad class of products described as sulfonates results from reactions that create a carbon-sulfur bond and utilizes sulfur VI reagent SO3 and its derivatives and adducts such as sulfuric acid. A smaller number of sulfonate products are prepared using sulfur IV reagent SOj as well as its derivatives and adducts such as sodium bisulfite. The preparation of sulfate esters involves the creation of carbon-oxygen-sulfur bonds, and can utilize SO3, sulfuric acid, or chlorosul-fonic acid to form alcohol sulfates that are labile and susceptible to hydrolysis in the presence of water as well as elimination reactions at elevated temperatures, and must be handled under milder conditions than sulfonates during formation and neutralization. Numerous older reviews and recent publications exist covering sulfonation and sulfation processes to produce surfactant products. " ... [Pg.17]

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