Oxygen sensors, porphyrin-based

Hartmann P., Trettnak W., Effects of polymer matrices on calibration functions of luminescent oxygen sensors based on porphyrin ketone complexes, Anal. Chem. 1996 68(15) 2615-2620. 

Vasil ev V, Borisov SM. Optical oxygen sensor based on phosphorescent metal porphyrins immobilized in perfluorinated ion-exchange membrane. Sens Actuators 2002 B82 272-6. 

Zhao Y, Ye T, Chen H, Huang D, Zhou T, He C, Chen X (2011) A dissolved oxygen sensor based on composite fluorinated xerogel doped with platinum porphyrin dye. Luminescence 26(l) 29-34... 

Optical sensors for oxygen are among the few sensors, which have found practical application for process-monitoring and clinical diagnostics. They are generally based on compounds such as platinum porphyrins or ruthenium phenanthroline derivatives (Table 17) which show a decrease in luminescence upon exposure to molecular oxygen15. 

Abstract Pressure-sensitive paint (PSP) is applied to the areodynamics measurement. PSP is optical sensor based on the luminescence of dye probe molecules quenching by oxygen gas. Many PSPs are composed of probe dye molecules, such as polycyclic aromatic hydrocarbons (pyrene, pyrene derivative etc.), transition metal complexes (ruthenium(II), osumium(II), iridium(III) etc.), and metalloporphyrins (platinum (II), palladium(II), etc.) immobilized in oxygen permeable polymer (silicone, polystyrene, fluorinated polymer, cellulose derivative, etc.) film. Dye probe molecules adsorbed layer based PSPs such as pyrene derivative and porphyrins directly adsorbed onto anodic oxidised aluminium plat substrate also developed. In this section the properties of various oxygen permeable polymer for matrix and various dye probes for PSP are described. 

Duarte J, Luz R, Damos F, Tanaka AA, Kubota LT (2008) A highly sensitive amperranetric sensor for oxygen based on iron(ll) tetrasulfonated phthalocyanine and iron(in) tetra-(N-methyl-pyridyl)-porphyrin multilayers. Anal Chim Acta 612(1) 29—36... 

Electrochemical methods for NO determination offer several features that are not available with spectroscopic approaches. Perhaps the most important is the capability of microelectrodes to directly measure NO in single cells in situ, in close proximity to the source of NO generation. Figure 2 shows sensors that have been developed for the electrochemical measurement of NO. One is based on the electrochemical oxidation of NO on a platinum electrode (the classical Clark probe for detection of oxygen) and operates in the amperometric mode [17]. The other is based on the electrochemical oxidation of NO on conductive polymeric porphyrin (porphyrinic sensor) [24]. The Clark probe uses a platinum wire as a working electrode (anode) and a silver wire serves as the counterelectrode (cathode). The electrodes are mounted in a capillary tube filled with a sodium chlo-ride/hydrochloric acid solution separated from the analyte by a gas-permeable membrane. A constant potential of 0.9 V is applied, and direct current (analytical signal) is measured from the electrochemical oxidation of NO on the platinum anode. In the porphyrinic sensor, NO is catalytically oxidized on a polymeric metalloporphyrin... 

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