Oxygen chemical looping combustion

Cho, P., Mattisson, T., and Lyngfelt, A., Comparison of iron-, nickel-, copper- and manganese-based oxygen carriers for chemical-looping combustion, Fuel, 83(9), 1215,2004. 

Corbella, B.M. et al., Performance in a fixed-bed reactor of titania-supported nickel oxide as oxygen carriers for the chemical-looping combustion of methane in multicycle tests, I EC Res., 45(1), 157, 2006. 

Chemical Looping Combustion (CLC). CLC is an oxyfuel concept where combustion is achieved using a metal oxide as the oxygen carrier without mixing fuel and air. A schematic of CLC concept is shown in Figure 11.14. 

A modified gas turbine cycle, a H2-fueled chemical-looping combustion, has been proposed in Japan. The oxidizer air or oxygen is replaced by a solid metal oxide, e.g., NiO. An increase in the efficiency up to 66.8 % is predicted compared with 61.6 % as the best figure for H2/O2 cycles [23]. 

Kuusik, R., Trikkel, A., Lyngfelt, A. and Mattisson, T. (2009) High temperature behavior of NiO-based oxygen carriers for Chemical Looping Combustion. Energy Proce-dia, 1, 3885-3892. 

Gayan, R, de Diego, L.E., Garcfa-Labiano, F. et al. (2008) Effect of support on reactivity and selectivity of Ni-based oxygen carriers for chemical-looping combustion. Fuel, 87, 2641-2650. 

Leion, H., Lyngfelt, A., Johansson, M. et al. (2008) The use of ilmenite as an oxygen carrier in chemical-looping combustion. Chemical Engineering Research and Design,... 

Corbella, B.M. and Palacios, J.M. (2007) Utania-supported iron oxide as oxygen carrier for chemical-looping combustion of methane. Fuel, 86,113-122. 

Proll, T, Mayer, K., Bolh -Nordenkampf, J. etal. (2009) Natural minerals as oxygen carriers for chemical looping combustion in a dual circulating fluidized bed system. Energy Procedia, 1, 27-34. 

Garcfa-Labiano, E., de Diego, L.F., Gayan, P. et al. (2009) Effect of fuel gas composition in chemical-looping combustion with Ni-based oxygen carriers. 1. fate of sulfur. Industrial Engineering Chemistry Research, 48,2499-2508. 

Forero, C.R., Gayan, P., Garcfa-Labiano, F. et al. (2010) Effect of gas composition in Chemical-Looping Combustion with copper-based oxygen carriers Fate of sulphur. International Journal of Greenhouse Gas Control, 4, 762-770. 

Lyngfelt, A. (2011) Oxygen carriers for chemical looping combustion - 4 000 h of operational experience. Oil Gas Science and Technology, 66,161-172. 

Linderholm, C., Lyngfelt, A., Cuadrat, A. and Jerndal, F. (2012) Chemical-looping combustion of solid fuels - Operation in a lOkW unit with two fuels, above-bed and in-bed fuel feed and two oxygen carriers, manganese ore and ilmenite. Fuel, 102, 808-822. 

Xiao, R., Chen, L Saha, C. et al. (2012) Pressurized chemical-looping combustion of coal using an iron ore as oxygen carrier in a pilot-scale unit. International Journal of Greenhouse Gas Control, 10,363-373. 

Shen, L., Wu, J., Xiao, J. et al. (2009) Chemical-looping combustion of biomass in a 10 kWth reactor with iron oxide as an oxygen carrier. Energy Fuels, 23, 2498-2505. 

Song, T Shen, L Zhang, H Gu, H Zhang, S Xiao and J. (2012) Chemical looping combustion of two bituminous coal / char with natural hematite as oxygen carrier in 1 kW th reactor. Proc. 2nd Int. Conf. Chem. Looping, Darmstadt, pp. 26-28. 

Wolf, J Anheden, M. and Yan, J. (2005) Comparison of nickel- and iron-based oxygen carriers in chemical looping combustion for CO capture in power generation. Fuel, 84, 993-1006. 

In this book, we have collected, in 11 chapters, information on novel possible intensified methods and reactors for sustainable energy conversion, including-but not limited to - novel concepts for chemical looping combustion, PI concepts for CO2 capture, oxy-ftiel and oxygen permeable membranes, blue energy and biomass conversion. 

Schematic of chemical-looping combustion (CLC). The oxygen carrier ( Me ) is oxidized to form MeO in the air reactor" (or oxidizer ), separated in a cyclone, and transferred into the fuel reactor (or reducer ) where it supplies the oxygen for fuel combustion and is thus reduced back to M . Transfer back to the air rector closes the loop .

Tian H, Simonyi T, Poston J, Siriwardane R. Effect of hydrogen sulfide on chemical looping combustion of coal-derived synthesis gas over bentonite-supported metal-oxide oxygen carriers. Ind Eng Chem Res 2009 48 8418. 

Ksepko E, Siriwardane RV, Tian H, Simonyi T, Scia,zko M. Comparative investigation on chemical looping combustion of coal-derived s3mthesis gas containing H2S over supported NiO oxygen carriers. Energy Fuels 2010 24 4206. 

Solunke RD, Veser G. Nanocomposite oxygen carriers for chemical-looping combustion of sulfur-contaminated S5mthesis gas. Energy Fuels 2009 23 4787. 

Schwebel GL, Leion H, Kruinm W. Comparison of natural ibnenites as oxygen carriers in chemical-looping combustion and influence of water gas shift reaction on gas composition. Chem Eng Res Des 2012 90 1351. 

Adanez J, Dueso C, de Diego LF, Garcia-Labiano F, Gayan P, Abad A. Effect of fuel gas composition in chemical-looping combustion with Ni-Based oxygen carriers. 2. Fate of bght hydrocarbons, bid Eng Chem Res 2009 48 2509. 

Cao Y, Casenas B, Pan WP. Investigation of chemical looping combustion by solid fuels. 2. Redox reaction kinetics and product characterization with coal, biomass, and sobd waste as solid fuels and CuO as an oxygen carrier. Energy Fuel 2006 20 1845. 

Saha C, Bhattacharya S. Comparison of CuO and NiO as oxygen carrier in chemical looping combustion of a Victorian brown coal, bit J Hydrog Energy 2011 36 12048. 

Gao ZP, Shen LH, Xiao J, Qing CJ, Song QL. Use of coal as fuel for chemical-looping combustion with Ni-based oxygen carrier. Ind Eng Chem Res 2008 47 9279. 

Shen L, Wu J, Xiao J. Experiments on chemical looping combustion of coal with a NiO based oxygen carrier. Combust Flame 2009 156 721. 

Leion H, Jemdal E, Steenari B-M, Hermansson S, Israelsson M, Jansson E, et al. Solid fuels in chemical-looping combustion using oxide scale and unprocessed iron ore as oxygen carriers. Fuel 2009 88 1945. 

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