Oxygen charge

Fig. 31 Substrate-oxygen charge transfer band onsets as a function of the ionization potentials of the substrates.

Pidko, E.A. and van Santen, R.A. (2006). Confined space-controlled olefin-oxygen charge transfer in zeolites. J. Phys. Chem. B 110, 2963-2967... 

Matsubara, C. and Kojima, M. (2001). Photo-oxygenation and photodimerization of 4-methoxystyrene in NaY. The role of co-adsorbed water and ankene-oxygen charge-transfer complex. Res. Chem. Int. 27, 975-989... 

In Equation (5) the exeess oxygen charge is compensated by cation vacancies (noted here as ( )) following the suggestions of van Roosmalen et al [38],... 

Figure 17 Photooxygenation via an oxygen-charge transfer complex.

Figure 18 Rate expressions for reaction via an oxygen-charge complex.

B (oxygen centered) Oxygen charge Hydrogen charge... 

Take as an example the oxygen charge-transfer reaction + 0o 0 + V0 + 2e ... 

Fig 6 Calculated Static Impulse vs Dimensionless Radius for Detonation (solid line) and Deflagration (dashed line) of Large Hydrogen-Oxygen Charge... 

In contrast to singlet oxygen, charged intermediates cannot penetrate ionic liquid-liquid interphases (ionic micelles or microemulsions) owing to charge repulsion or attraction [23]. Sensitizer and substrate solubilization in different phases may therefore be of interest for an improvement of chemical yield. 

Oxygen charge V in monomeric complexes in a solution do not have to be compensated according to Hiemstra et al [31] ... 

Our recent study (Ref. 31) on the internal oxidation of Ag-I.2 at% Mg and Ag-0.25 at% Mg-0.25 at% Ni showed that the clustering of oxygen active elements, R, with oxygen atoms O, varied with the ratio r = (0/R). The lower amount of R in the alloy has higher r-values Temperature dependent r-values indicated that lower temperatures showed higher r-values. Therefore, we can apply these phenomena in the oxygen-charging step or the CVD process. 

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