Oxidative oxoacids

Not only molecules with LLPCN > 4, but all molecules of the elements in period 3 and beyond in their higher valence states, including most of their numerous oxides, oxoacids, and related molecules such as SO3 and (H0)2S04 should be regarded as hypervalent if AO bonds are described as double bonds (1). However, Lewis did not regard these molecules as exceptions to the octet rule because he wrote the Lewis structures of these molecules with single bonds and the appropriate formal charges (2). 

Oxygen has major uses in the chemical industry too. It is used to oxidize methane, ethylene, and other hydrocarbons. Oxidation of methane produces synthesis gas. Ethylene oxidation yields products such as ethylene oxide, acetaldehyde, and acetic acid. Oxygen also is used in making many commercial inorganic compounds including various metal oxides, oxoacids, and 0x0-salts. 

Figure 15-15 Sequence of reactions catalyzed by a-oxoacid dehydrogenases. The substrate and product are shown in boxes, and the path of the oxidized oxoacid is traced by the heavy arrows. The lipoic acid "head" is shown rotating about the point of attachment to a core subunit. However, a whole flexible domain of the core is also thought to move.

Halogen Oxides, Oxoacids, and Oxoanions The Group 7A(17) elements form many oxides that are powerful oxidizing agents. Dichlorine monoxide (CI2O), chlorine dioxide (CIO2, with an unpaired electron and Cl in the unusual -t-4 oxidation state), and dichlorine heptaoxide (CLOy) are important examples. 

Oxides, oxoacids and hydroxides Oxides and oxoacids of carbon... 

SOME COMMON NITROGEN ELECTROPHILES OXIDES, OXOACIDS, AND OXOANIONS... 

Discuss key features of Group 5A(15), especially patterns in oxidation state, oxide acidity, and hydride and halide structures and describe the nitrogen and phosphoms oxides, oxoacids, and oxoanions ( 14.6) (EPs 14.46-14.56)... 

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