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Oxidation unsaturated bond oxidations

In the coordination unsaturated compounds (which are able to coordinate with one or two ligands) such as the Wilkinson complex, an aldehyde carbonyl, nitrogen group of diazo compound and carbon-carbon unsaturated bond oxidatively add to the compounds, and the cyclization is liable to proceed by reductive elimination [98-102]. For example, 4-pentene-l-al derivative reacts in the presence of the Wilkinson complex to afford prostaglandin derivatives by cyclization [98,101]. When the reaction is performed with a chiral rhodium complex, the cyclization product is obtained in a high ee% yield [102]. The cyclization usually forms five or six-membered ring compounds, the reaction of a diazo compound with acetylenic... [Pg.405]

Note Jones reagent is a solution of chromium trioxide or potassium dichromate in dilute sulfuric acid and acetone. Acetone markedly affects the properties of chromic acid. Oxidation is very rapid, usually exothermic, and the yields are typically high. This reagent rarely oxidizes unsaturated bonds. [Pg.205]

Pd-cataly2ed reactions of butadiene are different from those catalyzed by other transition metal complexes. Unlike Ni(0) catalysts, neither the well known cyclodimerization nor cyclotrimerization to form COD or CDT[1,2] takes place with Pd(0) catalysts. Pd(0) complexes catalyze two important reactions of conjugated dienes[3,4]. The first type is linear dimerization. The most characteristic and useful reaction of butadiene catalyzed by Pd(0) is dimerization with incorporation of nucleophiles. The bis-rr-allylpalladium complex 3 is believed to be an intermediate of 1,3,7-octatriene (7j and telomers 5 and 6[5,6]. The complex 3 is the resonance form of 2,5-divinylpalladacyclopentane (1) and pallada-3,7-cyclononadiene (2) formed by the oxidative cyclization of butadiene. The second reaction characteristic of Pd is the co-cyclization of butadiene with C = 0 bonds of aldehydes[7-9] and CO jlO] and C = N bonds of Schiff bases[ll] and isocyanate[12] to form the six-membered heterocyclic compounds 9 with two vinyl groups. The cyclization is explained by the insertion of these unsaturated bonds into the complex 1 to generate 8 and its reductive elimination to give 9. [Pg.423]

Dia ene deductions. Olefins, acetylenes, and azo-compounds are reduced by hydrazine in the presence of an oxidizing agent. Stereochemical studies of alkene and alkyne reductions suggest that hydrazine is partially oxidized to the transient diazene [3618-05-1] (diimide, diimine) (9) and that the cis-isomer of diazene is the actual hydrogenating agent, acting by a concerted attack on the unsaturated bond ... [Pg.277]

Oxidation. Ketones are oxidized with powerful oxidizing agents such as chromic or nitric acid. During oxidation, carbon—carbon bond cleavage occurs to produce carboxyHc acids. Ketone oxidation with hydrogen peroxide, or prolonged exposure to air and heat, can produce peroxides. Concentrated solutions of ketone peroxides (>30%) may explode, but dilute solutions are useful in curing unsaturated polyester resin mixtures (see... [Pg.487]

Reduced nicotinamide-adenine dinucleotide (NADH) plays a vital role in the reduction of oxygen in the respiratory chain [139]. The biological activity of NADH and oxidized nicotinamideadenine dinucleotide (NAD ) is based on the ability of the nicotinamide group to undergo reversible oxidation-reduction reactions, where a hydride equivalent transfers between a pyridine nucleus in the coenzymes and a substrate (Scheme 29a). The prototype of the reaction is formulated by a simple process where a hydride equivalent transfers from an allylic position to an unsaturated bond (Scheme 29b). No bonds form between the n bonds where electrons delocalize or where the frontier orbitals localize. The simplified formula can be compared with the ene reaction of propene (Scheme 29c), where a bond forms between the n bonds. [Pg.50]

As shown in Table 6 and Figure 1, the oxidation potentials of 2-substituted norbornadienes (1), 2-substituted bicyclo[2.2.2]octa-2,5-dienes (2) and 4-substituted [2.2]paracyclophanes (3) clearly indicate that the transannular interaction between two double bonds contributes already at the stage of the first electron transfer. Namely, in compounds 1-3, the electron is transferred from the unsaturated bond which is not substituted by the electron-withdrawing group, Figure 1 shows the... [Pg.762]

ADDITION OF NITRIC ACID, NITROGEN OXIDES AND RELATED COMPOUNDS TO UNSATURATED BONDS... [Pg.3]

A very active elemental rhodium is obtained by reduction of rhodium chloride with sodium borohydride [27]. Supported rhodium catalysts, usually 5% on carbon or alumina, are especially suited for hydrogenation of aromatic systems [iTj. A mixture of rhodium oxide and platinum oxide was also used for this purpose and proved better than platinum oxide alone [i5, 39]. Unsaturated halides containing vinylic halogens are reduced at the double bond without hydrogenolysis of the halogen [40]. [Pg.7]

The direct oxidation (M + O-,) of organic compounds by ozone is a selective reaction with slow reaction rate constants, typically being in the range of kD = 1.0 - 103 M 1 s. The ozone molecule reacts with the unsaturated bond due to its dipolar structure and leads to a splitting of the bond, which is based on the so-called Criegee mechanism (see Figure 2-2). The Criegee mechanism itself was developed for non-aqueous solutions. [Pg.14]


See other pages where Oxidation unsaturated bond oxidations is mentioned: [Pg.678]    [Pg.548]    [Pg.678]    [Pg.888]    [Pg.273]    [Pg.158]    [Pg.20]    [Pg.30]    [Pg.51]    [Pg.888]    [Pg.193]    [Pg.280]    [Pg.788]    [Pg.331]    [Pg.171]    [Pg.56]    [Pg.111]    [Pg.121]    [Pg.546]    [Pg.953]    [Pg.963]    [Pg.378]    [Pg.953]    [Pg.963]    [Pg.213]    [Pg.789]    [Pg.47]    [Pg.1188]    [Pg.888]    [Pg.44]    [Pg.266]    [Pg.442]    [Pg.290]    [Pg.525]   
See also in sourсe #XX -- [ Pg.678 ]

See also in sourсe #XX -- [ Pg.678 ]




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Oxides bonding

Unsaturated bond

Unsaturated oxidation

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