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Overview Generalities

Ion homeostasis was undoubtedly one of the earliest attributes of living cells. The maintenance of optimal concentrations of catalytic ions and ionic osmolytes is essential for the conduct of metabolism. Cells, both prokaryotic and eukaryotic, must be especially selective with regard to transition metal ions that cross the cell membranes. Not only must cells accumulate essential metal ions and exclude toxic ions, but they must also limit the influx or stimulate the efflux of essential metal ions so that these ions do not reach toxic levels. Both copper and iron, for example, are essential trace cations that can cause cellular damage if the internal cellular concentration of either cation is too high, or if the storage of these cations becomes deranged. [Pg.435]

Chemical coordination of metal ions in living systems is a central question in metal ion homeostasis and is under intense study. The predominant atoms that coordinate with the metals are oxygen, nitrogen, and sulfur. However, sometimes metals can form covalent bonds with carbon (e.g., methylmercury). Oxygen is used to coordinate transition metals for transport in the case of siderophores (e.g., enterochelin and aerobactin), but examples of proteins using oxygen atoms on amino acid side chains to coordinate metals are rare. Sulfur on cysteine or methionine residues is a common coordinating atom. Examples of cysteine coordination with [Pg.435]


Factors Affecting HETP An Overview Generally, packing efficiency increases (HETP decreases) when the following occur. [Pg.63]

We have tried to give an overview, general, and comprehensive, but not necessarily complete and exhaustive, of chiral structures associated with macrocyclic compounds known in the broadest sense as calixarenes. Necessarily, the picture arising in this way is complex and heterogeneous, perhaps even confusing. We hope, however, that we have at least left the reader with a feeling for the fascination that may be connected with such chiral structures and for the various possibilities that exist for calixarenes. [Pg.221]

OVERVIEW GENERAL CAPABILITIES OF ETV-ICPMS FOR TRACE ANALYSIS OF POLYMERS... [Pg.1073]

Table 5.2.-1 BUYER COUNTRY OVERVIEW GENERAL DATA (1982)... Table 5.2.-1 BUYER COUNTRY OVERVIEW GENERAL DATA (1982)...
Figure 9.18 provides an overview of the application envelope and the respective advantages and disadvantages of the various artificial lift techniques. As can be seen, only a few methods are suited for high rate environments gas lift, ESP s, and hydraulic systems. Beam pumps are generally unsuited to offshore applications because of the bulk of the required surface equipment. Whereas the vast majority of the world s artificially lifted strings are beam pumped, the majority of these are stripper wells producing less than 10 bpd. [Pg.232]

To gain a general overview on data and its pre-processing for learning... [Pg.203]

An overview of the general principles of filtration having specific appHcation to bacterial and viral removal is given herein. The emphasis is on ensuring that the sterility and/or safety of biologicals and biopharmaceuticals be maintained. [Pg.139]

This article addresses the synthesis, properties, and appHcations of redox dopable electronically conducting polymers and presents an overview of the field, drawing on specific examples to illustrate general concepts. There have been a number of excellent review articles (1—13). Metal particle-filled polymers, where electrical conductivity is the result of percolation of conducting filler particles in an insulating matrix (14) and ionically conducting polymers, where charge-transport is the result of the motion of ions and is thus a problem of mass transport (15), are not discussed. [Pg.35]

Mechanical flotation machines are most commonly used in the mineral industiy, while pneumatic column-type units are gaining popularity in recent years. Surveys by Harris (1976), Young (1982), Bar-beiy (1982), and Mavros (1991) provide a detailed overview of the process-engineering aspec ts of mineral flotation devices in particular and systems in general. [Pg.1813]


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