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RNi acquires durability toward corrosion from acetylacetone (AA) (CH3—CO—CH2—CO—CH3) by modification (J0). Table XXI shows the amount of corroded nickel in the reaction system from the catalyst when the hydrogenation of A A (10 ml) with RNi or MRNi (400 mg) was carried out at 65 C under 100 kg/cm2 of initial hydrogen pressure and was stopped at the point where 1 mol of hydrogen had been consumed. The durability of [Pg.248]

Effect of Modification on Amount of Corroded Ni with A A from the Catalyst  [Pg.248]

MRNi was found to correlate with the chelating ability of the modifying reagent. However, as mentioned in Section III,A, the hydrogenation activity of the catalyst was not affected, but rather enhanced, by the modification. The phenomenon which has a close connection with the above finding was observed in the hydrogenation of MAA mentioned in Section III,B. The hydrogenation of MAA with RNi could not be carried out at atmospheric pressure due to corrosion of the catalyst by MAA (32, 34). [Pg.249]

The above findings suggest that both MAA and AA have difficulty in chelating the nickel surface of the MRNi catalyst. That is, MAA and AA have difficulty in adsorbing on the surface of the catalyst due to hindrance by the modifying reagent. [Pg.249]


Processing changes etc.) profiles in three other profiles in additional change (level II) Annual report... [Pg.83]

Postforming identifies plastic sheet, rods, tubes, and other profile shapes that are formed into different shapes (coils, corrugated tubings, tubular nets, etc. Its major use is inline with an extruder processing... [Pg.331]

Lend themselves to adaptation for other profiles, e.g., coating for sustained release... [Pg.236]

Westlane Plastics (USA) [45] uses an extrusion method to produce rods of up to 31.75 mm diameter, stri K, pipes with 9.52-12.7 mm wall thickness and other profile artides from compositions based on phenol, melamine, carbamide, and alkyd resins. Fillers used incluse wood crush, cellulose, chalk, talc, clay, mica, silica, coke, graphite, and carbon fibers. [Pg.57]

The column profiles with the optimum conditions determined in Example 1.1 are shown in Figure 4.17. The poor features shown in the other profiles are absent. [Pg.184]

To further improve the fit, the following parameters were consequently included into the least squares minimization strain peak broadening parameter Y, then peak asymmetry a, and sample displacement. At this point, a linear background was substituted by a fourth order shifted-Chebyshev polynomial and refined with all other profile parameters fixed. Finally, all relevant parameters were refined together. The convergence was achieved, and the final fit, which is illustrated in Figure 7.41, is quite satisfactory considering the poor resolution of the powder diffraction pattern. [Pg.682]

Fragrance profiles are often presented as a series of complex tables or graphs from which patterns, order or exceptions need to be found. Looking at individual profiles it is possible to determine the main odour characteristics. Comparison with the other profiles establishes the main differences between them. [Pg.151]

The current method employs a series of glycerol-water mixed solutions. Glycerol and water are fully compatible liquids. Neat glycerol has the density of 1.25 g/cm, water 1.0 g/cm. Hence, density of WPC materials (in this particular case) in the range of 1.0-1.25 g/cm can be measured, practically with accuracy up to 0.002 g/cm. When a specimen (a full cross-section of a deck board or other profile) is... [Pg.216]

One can see that in Run 1 a mixture of two HDPE was used, both of which had rather low power-law index values (0.40 and 0.42), and the second one had a significantly lower value of the critical shear rate (300 s ). What is worse, the regrind, used in the amount of 15% in the final mix, had an exceptionally low critical shear rate (50 s ) along with a rather low value of the power-law index (0.32). This means that the processing window for this combination was quite narrow, and a slight increase in a flow rate would result in melt fracture, board roughness, sharkskin, and other profile defects (Figs. 17.10-17.14, and 17.19-17.23). [Pg.660]

This section discusses the fabrication of PTFE, known asfine powder or coagulated dispersion powder, into shapes and articles. The most common fabricated commercial forms include rods, tapes, wire insulation, tubing, sheeting, and other profiles. Tube diameters range from a fraction of a millimeter to almost a meter with wall thicknesses of 100 pm to a few millimeters. Rods up to 5 cm diameter can be produced and calendared, prior to sintering, to produce tapes. Unsintered tapes are broadly applied as... [Pg.174]


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