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Oscillating absorbance

In this s is the absorption cross section of the oscillating absorber, Us the steady part of the thermal neutron density, a the amplitude of the oscillation. Because of the 6 functions, one can replace in (18) ris x y z) by... [Pg.537]

When monochromatic radiation falls on a molecular sample in the gas phase, and is not absorbed by it, the oscillating electric field E (see Equation 2.1) of the radiation induces in the molecule an electric dipole which is related to E by the polarizability... [Pg.125]

One characteristic property of dyes is their colour due to absorption from the ground electronic state Sq to the first excited singlet state Sj lying in the visible region. Also typical of a dye is a high absorbing power characterized by a value of the oscillator strength/ (see Equation 2.18) close to 1, and also a value of the fluorescence quantum yield (see Equation 7.135) close to 1. [Pg.359]

Fig. 1. An incident electromagnetic field of intensity, having an associated electric field, U, induces dipole oscillation in the absorbers. The transmitted... Fig. 1. An incident electromagnetic field of intensity, having an associated electric field, U, induces dipole oscillation in the absorbers. The transmitted...
Noise Control Sound is a fluctuation of air pressure that can be detected by the human ear. Sound travels through any fluid (e.g., the air) as a compression/expansion wave. This wave travels radially outward in all directions from the sound source. The pressure wave induces an oscillating motion in the transmitting medium that is superimposed on any other net motion it may have. These waves are reflec ted, refracted, scattered, and absorbed as they encounter solid objects. Sound is transmitted through sohds in a complex array of types of elastic waves. Sound is charac terized by its amplitude, frequency, phase, and direction of propagation. [Pg.788]

The damping strength of the object is such that it may absorb most of its restoritig force before it reaches its original position. There are no oscillations. For overdamped systems, rj > I. [Pg.447]

Reactive control is also possible through synchronous condensers. As they rotate, the rotor stores kinetic energy which tends to absorb sudden Huctuations in the supply system, such as sudden loadings. They are. however, sluggish in operation and very expensive compared to thyristor controls. Their rotating masses add inertia, contribute to the transient oscillations and add to the fault level of the system. All these factors render them less suitable for such applications. Their application is therefore gradually disappearing. [Pg.806]

Self-absorption occurs when the path-length is too large [35] and the X-rays emitted have a significant probability of being absorbed by the remainder of the sample before being detected. This has the consequence of reducing the amplitude of the EXAFS oscillations and producing erroneous results. As the sample becomes more dilute this probability decreases. All the atoms in the sample determine the amount of self-absorption hence the need for thin samples. [Pg.141]

The nature of the light emissions is influenced by the way in which the absorbed energy is transferred through the polymer matrix. In crystalline polymers, exciton migration is possible as all molecules lose their energetic individuality and all electronic and oscillation levels are coupled [20]. Thus, new exciton absorption and emission bands are formed and the excitation energy can move along the chain ... [Pg.401]

The classical scheme for dichroism measurements implies measuring absorbances (optical densities) for light electric vector parallel and perpendicular to the orientation of director of a planarly oriented nematic or smectic sample. This approach requires high quality polarizers and planarly oriented samples. The alternative technique [50, 53] utilizes a comparison of the absorbance in the isotropic phase (Dj) with that of a homeotropically oriented smectic phase (Dh). In this case, the apparent order parameter for each vibrational oscillator of interest S (related to a certain molecular fragment) may be calculated as S = l-(Dh/Di) (l/f), where / is the thermal correction factor. The angles of orientation of vibrational oscillators (0) with respect to the normal to the smectic layers may be determined according to the equation... [Pg.210]

In general photochemical reactions only occur when the affected substance absorbs radiation, i. e. when ti or n electrons are raised to an excited rt state. Interaction of the electric light vector with the electronic shell of the molecule brings about a change in the structure of the electronic shell. This change takes place during one period of oscillation of the light (ca. 10 s). The altered structure of the electronic shell cor-... [Pg.15]


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