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Origin modes

There are different strategies for the selection of sub-matrices for evolving type factor analyses. The classical, original mode has been presented so far. The most important alternative procedure is based on a moving window of fixed size. In other words, a window of a pre-defined number of consecutive spectra is moved along the columns of the matrix Y. Each window is subjected to SVD, the singular values are stored and their logarithms are plotted. [Pg.268]

A. Penicillin G structure and origin mode of action of penicillins methods for prolonging duration of action... [Pg.269]

Normal phase (NP) was the original mode of high-performance liquid chromatography (HPLC) reported. This uses a polar stationary phase (e.g. sihca, alumina) and non-polar mobile phase. It can also be referred to as adsorption... [Pg.96]

Sequential extraction procedures include successive sample treatment with a series of extractants selected on the basis of their ability to dissolve analytes bound to different components of the matrix. The use of sequential extraction procedures simulating natural phenomena, (e.g., acid rain), can deliver detailed information about the origin, mode of occurrence, physiological availability, and mobilization of trace elements. It is also possible to estimate toxicological risk ensuing from the presence of different forms of metals and various phases containing those metals. A... [Pg.137]

In modern terms, asphaltene is conceptually defined as the n-pentane-insoluble and benzene-soluble fraction whether it is derived from coal or from petroleum. There are a number of procedures used to isolate asphaltene (2-7), all of which appear to be reproducible (8) but do not necessarily provide equivalent end-products. The similarity between coal- and petroleum-derived asphaltenes begins and ends at the definition of the separation procedure. Puzinauskas and Corbett s (9) comments on asphalt may be paraphrased and applied to asphaltene. They state that the broad solvent classification is unfortunate it leads to misconceptions that petroleum and coal materials are alike, or at least similar. However, these two classes of materials differ not only in their origin, mode of manufacture and uses, but also in their chemical composition and physical behavior. [Pg.34]

Generic Name (structure) Trade Name Originator Mode of Action d Therapeutic Indication Total Daily Dose (mg) Dosing Schedule... [Pg.529]

Bio catalyst Form Origin Mode of immobilization Reference... [Pg.93]

So what happens if we change our consideration to a molecule of different complexity In practice, there are many variables which complicate the analysis, for not only will the and d change, but /<, and Aoo will also be different. Let us imagine a hypothetical molecule C3D3 which possesses the same internal relaxation rate constant as does cyclopropane, and which reacts to form some product with the same values of and of A. We will also assume that it has the same two moments of inertia as does cyclopropane, so that the only thing different about it is its vibrational frequencies it has 12 normal modes of vibration instead of 21, and for the purposes of this illustration, I have simply made an arbitrary deletion of nine of the original modes of the cyclopropane molecule. [Pg.54]

A number of methods have been used to convert catalytic species into a heterogeneous form, and thereby simplify separation from the reaction mixture, but without changing drastically the nature of the catalytic species, or its immediate environment. To ensure that the original mechanistic pathway is unaffected, this category must exclude the substitution of a supported metal for a soluble metal compound or complex. The original modes of decay and interference by poisons are then similarly unaffected. [Pg.317]

We assume that ki=K2=Ks=k and so the damping terms for the collective modes have the same form as for the original modes. [Pg.92]

The observed switch of Oreina leaf beetles from their original mode of defense (i. e., antogenous production of cardenolides) to host-derived defense (i.e., sequestration of PAs) intensified the discussion about the evolution of host plant affiliation and chemical defense in leaf beetles [108,115]. Evolutionary scenarios favor the role of PAs as efficient defensive compound. Recently, it was... [Pg.230]

Oxidative addition to chelate catalyst-substrate complexes Since the chelating catalyst-substrate complexes with different mode of double bond coordination are diastereomers, they have different chemical properties, in particular, the rates of oxidative addition musf be different. Moreover, it is clear that hydrogen atoms must come from fhe side of rhodium. Hence, if the oxidative addition is irreversible and the double bond does not dissociate before, during, or affer fhe oxidative addition, the original mode of the double bond coordination could determine the stereochemical outcome of the reaction via the difference in reactivities of the corresponding catalyst-substrate complexes. This is the main idea of the so-called unsaturated mechanism of stereoselection (Scheme 1.13). - ... [Pg.15]

By applying the transformation TsxVs to the original modes of the environment. [Pg.289]


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See also in sourсe #XX -- [ Pg.197 ]




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