Organotin hydrides Subject

Organotin hydrides have found much interest in recent years both as synthetic reagents and as the subjects of numerous theoretical investigations. 

When subjected to organotin hydride reduction mediated by AIBN, an a,y3-... 

It has been reported that subjection of an 11-membered macrocycle involving an alkyne and alkenes to a radical cyclization procedure leads to a tandem cyclization giving rise to the formation of a fused 6,7-bicychc framework [249]. It should be mentioned that the in situ methodology for generation of organotin hydride works... 

The subject index provides access to the text by way of methods, techniques, reaction types, apparatus, effects and other phenomena. Also, it lists compound classes such as organotin compounds or rare-earth hydrides which cannot be expressed by the empirical formulas of the compound index. 

Reductive Desulfonylations by Tin Hydrides. Reductive desulfonylation of allyl, vinyl, and a-functionalized sulfones can be carried out employing tin hydrides. This radical reaction is usually promoted thermally or photochemically and provides organotin derivatives as intermediates which are finally subjected to protonolysis (Eq. 32). Both steps can be carried out in one pot employing catalytic amounts of tin. 

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