Order-disorder transition temperatures

Figure 6.10. Dilatotneuic record of a sample of a Ni-AI-Fe alloy in the neighbourhood of an order-disorder transition temperature (Cahn ei al. 1987).

Those Warren-Cowley parameters have been determined in situ above the order-disorder transition temperature by diffuse neutron scattering. From these experimentally determined static correlations, the first nine effective pair interactions have been deduced using inverse Monte Carlo simulations. 

There are few reports on block-copolymeric TPE (namely, polyurethane, EVA, SBS, poly (styrene-fo-butyl acrylate) (PSBA))-clay nanocomposites also [196-199]. Choi et al. [196] studied the effect of the silicate layers in the nanocomposites on the order-disorder transition temperature of... 

Transition Temperature. The order-disorder transition temperature mid-point T is also determined both by the environment - salinity, pH value, and the nature of the ions in solution, and the structure of the polymer - charge, pyruvate, succinate and acetate content. Most published work describes the low salinity behaviour of such polymers, and has shown that for xanthan, the transition temperature exceeds 100 C as the salinity exceeds about 1 per cent sodium chloride (10). 

The order-disorder transition temperature is a crucial parameter for biopolymers like Shellflo-S and xanthan, as it controls both rheology and breaking sensitivity. 

The Inden model [20] is frequently used to describe second-order magnetic order-disorder transitions. Inden assumed that the heat capacity varied as a logarithmic function of temperature and used separate expressions above and below the magnetic order-disorder transition temperature (TtIS) in order to treat the effects of both long- and short-range order. Thus for z = (T/TtIS) < 1 ... 

Fig. 1.22 Ln versus a for S = 0.5 (eqn (1.117)). The insert shows the In versus a curve, on which the order-disorder transition temperature, is clearly seen.

Fig. 18 Order-disorder transition temperature (Todt) as a function of the electric field strength of a 32.5 wt% solution of SI in toluene. The temperatures have been obtained during cooling open circles) and heating cycles (solid circles) of the solution. The dashed line at 53.0°C refers to the constant temperature experiment in Fig. 19. Reprinted with permission from Macromolecules [72]. Copyright 2009 American Chemical Society...

Schoberth HG et al (2009) Shifting the order-disorder transition temperature of block copolymer systems with electric fields. Macromolecules 42(10) 3433-3436... 

To determine the order disorder transition temperature, which is usually called the N6el temperature TV in antiferromagnets, but the... 

Hydrogenated SBCs are often used to modify polyolefins such as polypropylene, polybutylene and polyethylene. One of the unique characteristics of strongly phase-separated block copolymers such as high molecular weight (>50 000) SEBS and SEPS is their response to shear in the melt. These polymers retain their phase-separated structure well above the Tg of the polystyrene because their order-disorder transition temperatures are above processing temperatures. This phase separation strongly inhibits flow in the absence of shear resulting in infinite viscosity at zero shear rates. The application of shear... 

Table 23.4 Order-disorder transition temperatures of hydrogenated poly(styrene-block-diene) copolymers...

A fully microscopic interpretation of the temperature dependence of the absorption maximum, even well above any order-disorder transition temperature, is a formidable task because of the potential importance of many complicated physical factors (27-30). As a first attack on this problem, we have adopted a simple mean-field (or effective-medium) approach (28-30) with the assumption that the absorption peak (to) is linearly perturbed from its limiting dl -trans value ((Orod) by the presence of bond rotational defects (free energy of formation, e)... 

Table II. Order-Disorder Transition Temperatures and Widths of High-Molecular-Weight Polysilylenes ...

Figure 13.15 Reduced storage modulus versus reduced frequency arco for a lamellae-forming polystyrene-polyisoprene diblock copolymer (M = 22,000) at temperatures above the order-disorder transition temperature Todt = 152°C, and quenched to temperatures below it. The disordered samples show terminal behavior, and the ordered (but unoriented) ones show nonterminal behavior. (Reprinted with permission from Patel et al.. Macromolecules 28 4313. Copyright 1995, American Chemical...

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